苯酚型硼氮配位酚醛树脂的热性能与热降解动力学

doi:10.3969/j.issn.1000-1565.2008.03.015

河北大学学报(自然科学版) ›› 2008, Vol. 28 ›› Issue (3): 282-286,290.DOI: 10.3969/j.issn.1000-1565.2008.03.015

苯酚型硼氮配位酚醛树脂的热性能与热降解动力学

翟丁,高俊刚,田庆,蒋超杰

河北大学,化学与环境科学学院,河北,保定 071002

出版日期:2008-05-25 发布日期:2008-05-25

Thermal Degradation Kinetics and Thermal Properties of Boron-nitrogen Coordination Phenol-formaldehyde Resin

ZHAI Ding,GAO Jun-gang,TIAN Qing,JIANG Chao-jie

Online:2008-05-25 Published:2008-05-25

摘要/Abstract

摘要： 用多聚甲醛法合成了苯酚型硼氮配位酚醛树脂,1H NMR和FTIR证明了其结构,用动态力学谱仪测定了玻璃化转变温度(Tg)与固化程度的关系,用热重法(TGA)分析了硼氮配位酚醛树脂的热分解动力学.结果表明树脂的玻璃化转变温度超过200℃,并随固化反应程度增加而提高,热分解过程为多阶段分解,且均符合一级动力学,热分解活化能随分解程度提高而增加.

中图分类号:

O634.3+1

翟丁,高俊刚,田庆,蒋超杰. 苯酚型硼氮配位酚醛树脂的热性能与热降解动力学[J]. 河北大学学报(自然科学版), 2008, 28(3): 282-286,290.

ZHAI Ding,GAO Jun-gang,TIAN Qing,JIANG Chao-jie. Thermal Degradation Kinetics and Thermal Properties of Boron-nitrogen Coordination Phenol-formaldehyde Resin[J]. Journal of Hebei University (Natural Science Edition), 2008, 28(3): 282-286,290.

参考文献

[1] America Patash Chem Corp. Synthesis of boron-containing bisphenol-A formaldehyde resin: [P]. BP 957611 1964.
[2] Liu YF., Gao JG., Zhang RZ.. Thermal properties and stability of boron-containing phenol-formaldehyde resin formed from paraformaldehyde [J]. Polymer Degradation and Stability 2002, 3(3).
[3] Mohamed O.Abdalla, Adriane Ludwick, Temisha Mitchell. Boron-modified phenolic resins for high performance applications [J]. Polymer: The International Journal for the Science and Technology of Polymers 2003, 24(24).
[4] 徐庆衍. 硼氮配位结构的酚醛树脂 [J]. 河北大学学报(自然科学版) 1976, A-19.
[5] HOEFEL HEINZ-BERNHARD, KIESSLING HANS-JOACHIM DR, LAMPERT FRED DR. Verfahrenzur herstellung.hartbarer mad warmehartbare, borhahiger kunsthavze [P]. DE 2436358 1975.
[6] Jungang Gao, Xiaohui Su Liya. Synthesis and Structure Characterization of Boron-Nitrogen Containing Phenol Formaldehyde Resin [J]. International Journal of Polymeric Materials 2005, 10(10).
[7] 屠婉蓉, 魏守义. 甲醛水溶液法合成双酚-A型硼酚醛树脂 [J]. 塑料工业 1981.
[8] GAO J G, XIA L Y. Structure of a boron-containing bisphenal-F formaldehyde resin and kinetics of its thermal degradation [J]. Polymer Degradation and Stability 2004, 83.
[9] 黄世文, 单自兴, 黄金昆. 杂芳基硼化合物的合成 [J]. 武汉大学学报(自然科学版) 1999, 45(02).
[10] GILLHAM J K. The TBA torsion pendulum:a technique for Characterizing the cur and properties of thermosetting systems [J]. Polymer International 1997, 44.
[11] MIKROYANNIDIS J A, MELISSARIS A P. Heat-resistant adhesive resins derived from bismale imides and bisnadimides con-taining amide linkages [J]. Journal of Applied Polymer Science 1989, 37.
[12] MADHUSUDANAN PM, KRISHNAN K, NINAN K N. New approximation for the p(X) function in the evaluation of non-isothermal kinetic data [J]. Thermochimica Acta 1986, 97.

苯酚型硼氮配位酚醛树脂的热性能与热降解动力学

Thermal Degradation Kinetics and Thermal Properties of Boron-nitrogen Coordination Phenol-formaldehyde Resin

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 5

编辑推荐

Metrics

本文评价

[1]	尹纪伟,杜洁,王旭明,张芳华,李雪,李玮,张红蕾. 酚醛树脂基球形活性炭的制备及其吸附性能[J]. 河北大学学报(自然科学版), 2020, 40(3): 276-282.
[2]	庞秀言,宋明凯,翟志晓. 抗氧化性可膨胀石墨的制备及其阻燃性能[J]. 河北大学学报(自然科学版), 2014, 34(2): 166-173.
[3]	丁士文,李岩. 水热法制备纳米CaB6O10润滑油添加剂[J]. 河北大学学报(自然科学版), 2014, 34(2): 154-159.
[4]	王敏捷,张青,李春子,巴信武. 超支化不饱和聚(酰胺-酯)的改性及热分解动力学[J]. 河北大学学报(自然科学版), 2007, 27(3): 292-299.
[5]	闰明涛,王迎进,姚晨光,高俊刚. PET/PEN共混物的热分解行为及其动力学[J]. 河北大学学报(自然科学版), 2007, 27(1): 59-63.