氯菊酯在沙土表面的光降解

  • 刘芃岩 ,
  • 田磊 ,
  • 陈艳杰
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  • 河北大学化学与环境科学学院,河北保定,071002

网络出版日期: 2014-03-25

基金资助

国家自然科学基金资助项目,河北省教育厅重点项目

Photodegradation of permethrin on the sand surface

  • LIU Pengyan ,
  • TIAN Lei ,
  • CHEN Yanjie
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Online published: 2014-03-25

摘要

为了研究氯菊酯在土壤中的光降解规律,更好地为其在自然环境中的光降解提供理论依据,以沙土做基质,通过控制几个典型的环境因素,探讨氯菊酯在沙土表面光降解的规律.并利用气相色谱-质谱联用仪对降解中间产物进行分析,以便探讨氯菊酯在沙土中可能的降解过程.根据实际情况,主要选择了以下几种影响因素进行研究:样品与光源的距离、氯菊酯含量、沙土厚度、光源类型、pH及含水量、腐殖酸和几种土壤中常见的无机盐含量.结果表明:靠近光源,减少厚度,使用紫外光源和添加含铁无机盐均有利于氯菊酯在土壤表面降解.

本文引用格式

刘芃岩 , 田磊 , 陈艳杰 . 氯菊酯在沙土表面的光降解[J]. 河北大学学报(自然科学版), 2014 , 34(2) : 160 -165 . DOI: 10.3969/j.issn.1000-1565.2014.02.009

参考文献

[1] 刘大鹏, 钱万红, 姜志宽, 张应阔, 顾健, 孙俊. 氯菊酯在皮肤上的残留率与时间关系的研究 [J]. 中国媒介生物学及控制杂志 2000.doi:10.3969/j.issn.1003-4692.2000.04.014
[2] 黄晓会, 薛健, 吴晓波, 佟鹤芳, HUANG Xiao-hui, XUE Jian, WU Xiao-bo, TONG He-fang. 气相色谱法检测桑叶中有机氯及菊酯类农药 [J]. 分析科学学报 2012.
[3] 庄婉娥, 弓振斌, 叶江雷, 陈登云, ZHUANG Wan-E, GONG Zhen-Bin, YE Jiang-Lei, CHEN Deng-Yun. 凝胶渗透色谱净化-气相色谱-质谱法同时测定金银花中33种农药残留组分 [J]. 分析化学 2010.doi:10.3724/SP.J.1096.2010.00811
[4] 邴欣, 汝少国, BING Xin, RU Shao-guo. 四种拟除虫菊酯类农药的环境雌激素活性研究 [J]. 中国环境科学 2009.doi:10.3321/j.issn:1000-6923.2009.02.008
[5] 李玲玉, 刘艳, 颜冬云, 徐绍辉. 拟除虫菊酯类农药的降解与代谢研究进展 [J]. 环境科学与技术 2010.doi:10.3969/j.issn.1003-6504.2010.04.016
[6] LIU Ting-feng, SUN Cheng, TA Na, HONG Jun, YANG Shao-gui, CHEN Chuan-xiang. Effect of copper on the degradation of pesticides cypermethrin and cyhalothrin [J]. 环境科学学报(英文版) 2007.doi:10.3321/j.issn:1001-0742.2007.10.014
[7] Schleier JJ 3rd, Peterson RK. Toxicity and risk of permethrin and naled to non-target insects after adult mosquito management. [J]. Ecotoxicology 2010, 6(6).
[8] Carloni, M., Nasuti, C., Fedeli, D., Montani, M., Amici, A., Vadhana, M.S.D., Gabbianelli, R.. The impact of early life permethrin exposure on development of neurodegeneration in adulthood [J]. Experimental Gerontology 2012, 1(1).
[9] Reifenrath WG, Ross JH, Driver JH. Experimental methods for determining permethrin dermal absorption. [J]. Journal of toxicology and environmental health, Part A 2011, 1/6(1/6).
[10] Fernandez-Alvarez M, Lores M, Llompart M, Garcia-Jares C, Cela R. The photochemical behaviour of five household pyrethroid insecticides and a synergist as studied by photo-solid-phase microextraction [J]. Analytical and bioanalytical chemistry 2007, 5/6(5/6).
[11] LIU Pengyan, LIU Yujie, LIU Qingxue. Photodegradation mechanism of deltamethrin and fenvalerate original research article [J]. Journal of Environmental Sciences 2010, 22(07).
[12] COLY A, AARON J. Cyclodextrin-enhaneed fluorescence and photochemically-induced fluorescence determination of five aromatic pesticides in water [J]. Analytica Chimica Acta 1994, 360.
[13] Maria Fernandez-Alvarez, Maria Llompart, Carmen Garcia-Jares, Thierry Dagnac, Marta Lores. Investigation of the photochemical behaviour of pyrethroids lacking the cyclopropane ring by photo-solid-phase microextraction and gas chromatography/mass spectrometry [J]. Rapid Communications in Mass Spectrometry: RCM 2009, 23(23).
[14] SOVACS M F. EPA guidelines on environment fate [J]. Residue Reviews 1983, 85.
[15] TURNER E. An Assessment of test methods of photolysis of chemical in the environment of brussels, belgium:ecology and toxicology center [J]. European Chemical Industry 1981.
[16] 中华人民共和国农业部. 农药登记资料规定 [Z]. 2007.
[17] 毕刚, 田世忠, 冯子刚. 拟除虫菊酯与有机磷农药混合溶液的光敏降解 [J]. 环境科学学报 1996, 16(03).
[18] HAUTALA R R. Surfactant effects on pesticide photochemistry water and soil [M]. Environmental Protect ion Agency 1978.
[19] Miller PL, Chin YP. Photoinduced degradation of carbaryl in a wetland surface water. [J]. Journal of Agricultural and Food Chemistry 2002, 23(23).
[20] Vialaton D, Pilichowski JF, Baglio D, Paya-Perez A, Larsen B, Richard. Phototransformation of propiconazole in aqueous media [J]. Journal of Agricultural and Food Chemistry 2001, 11(11).
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