将NO脉冲流光放电的2个主要激发解离通道作为主要研究对象,依据不同电子激发温度下电子能量分布函数和电子激发态的碰撞激发函数,积分计算了脉冲流光放电下NO的2个主要激发解离通道的激发碰撞截面,并依据激发碰撞几率函数归一的原理,研究了NO 2个主要激发解离通道的竞争过程.N原子和N+特征谱线荧光辐射强度随电子激发温度变化的计算结果与本研究小组的实验结果符合得很好,验证了理论处理的合理性,也为NO分解过程研究提供了理论依据.
[1] 姜明, 程新路, 杨向东. 高密度氩等离子体电子密度的计算 [J]. 原子与分子物理学报 2004.doi:10.3969/j.issn.1000-0364.2004.03.012
[2] 张贵银. 氮氧化物电子态光谱研究及光学检测 [D]. 河北大学 2005.
[3] 王明星. 大气化学 [M]. 北京:气象出版社 1999.
[4] AMIROV R H, CHAE J O, DESSIATERIK Y N. Removal of NOx and SO2 from air excited by steamer corona:Experimental results and modeling [J]. Applied Physics 1998, 37.
[5] NAKAGAWA Y N, KAWAUCHI H K. Pulse intense electron beam irridiation on the atmospheric pressure containing 200 ppm of NO Jpn [J]. Applied Physics 1998, 37.
[6] WODTKE A M, HIWEL L, SCHLUTER H S. High sensitivity detection of NO in a flame using a tunable ArF laser [J]. Optics Letters 1988, 13.
[7] NELSON D D, ZAHNISER M S, MCMANUS J B. A tunable dionde laser system for the remote sensing of onroad vehicle emissions [J]. Applied Physics 1998, B67.
[8] Peng WX., Marshall A., Singhal RP., Ledingham KWD.. URBAN AIR POLLUTION MONITORING - LASER-BASED PROCEDURE FOR THE DETECTION OF NOX GASES [J]. The Analyst: The Analytical Journal of the Royal Society of Chemistry: A Monthly International Publication Dealing with All Branches of Analytical Chemistry 1995, 10(10).
[9] Rothe EW, Andresen P, MAX PLANCK INST STROMUNGSFORSCH D-3400 GOTTINGEN GERMANY.. Application of tunable excimer lasers to combustion diagnostics: A review [J]. Applied optics 1997, 18(18).
[10] HIRST BILL, GILLESPIE STEVE. Optical sensors:a path to better gas detection [J]. Physics World 1998.
[11] BRADSHAW J D, RODGERS M O, DAVIS D D. Single photon laser induced fluorescence detection of NO and SO2 for atmospheric conditions of composition and pressure [J]. Applied Optics 1982, 21.
[12] 程学良. 贫氧状态下NO脉冲放电解离过程 [D]. 保定:河北大学 2012.
[13] 汪志诚. 热力学统计物理 [M]. 北京:高等教育出版社 1993.
[14] 胡治强, 甄汉生, 施迎难. 气体电子学 [M]. 北京:电子工业出版社 1985.
[15] Itikawa Y.. Cross sections for electron collisions with carbon dioxide [J]. Journal of Physical and Chemical Reference Data 2002, 3(3).
[16] 丘军林. 气体电子学 [M]. 武汉:华中理工大学出版社 1999.
[17] 美国国家标准技术研究所. 原子线形光谱数据库 [EB/OL]. http://physics.nist.gov/PhysRefData/ASD/lines_form.html 2012.
[18] GERHARD HERZBERG F R S. Molecular spectra and molecular structure I.spectra of diatomic molecules [M]. Canada:D Van Nostrand Company, INC 1950.