以铁(Ⅱ)-邻二氮菲络合物(Fe(Ⅱ)/phen)为催化体系，以苄氯为引发剂，对苯乙烯的原子转移自由基聚合及苯乙烯与甲基丙烯酸丁酯的嵌段共聚进行了研究.发现本体系可有效地控制聚合物的相对分子质量分布(1.2
[1] Wang J S, MATYJASZEWSKI K. Controlled/Living radical polymerization atom trasfer radical polymerization in the presence of transition-metal complexes [J]. Journal of the American Chemical Society 1995, 117(20).
[2] Kato M, KAMIGAITO M, SAWAMOTO M. Polmerization of methyl methacrylate with the carbon tetrachloride/dichlorotris-(triphenyl phosphine) ruthenium/methyl-aluminum bis(2 6-di-tert-butylphenoxide) initiating system: possibility of living radical polymerizaton [J]. Macromolecules 1995, 28(05).
[3] Wang JS., Matyjaszewski K.. CONTROLLED LIVING RADICAL POLYMERIZATION - HALOGEN ATOM TRANSFER RADICAL POLYMERIZATION PROMOTED BY A CU(I)CU(II) REDOX PROCESS [J]. Macromolecules 1995, 23(23).
[4] Uegaki H., Kamigaito M., Sawamoto M., Kotani Y.. NICKEL-MEDIATED LIVING RADICAL POLYMERIZATION OF METHYL METHACRYLATE [J]. Macromolecules 1997, 8(8).
[5] Ando T, KATO M, KAMIGAITO M. Living radical polymerization of methyl methacrylate with ruthenium complex: formation of polymers with controlled molecular weights and very narrow distributions [J]. Macromolecules 1996, 29(03).
[6] Matyjaszewski K., Xia JH., Mcdermott NE., Wei ML.. CONTROLLED/LIVING RADICAL POLYMERIZATION OF STYRENE AND METHYL METHACRYLATE CATALYZED BY IRON COMPLEXES [J]. Macromolecules 1997, 26(26).
[7] Moineau G., Jerome R., Senninger T., Teyssie P., Dubois P.. Alternative atom transfer radical polymerization for MMA using FeCl3 and AIBN in the presence of triphenylphosphine: An easy way to well-controlled PMMA [J]. Macromolecules 1998, 2(2).
[8] LEE G M, WEINRED S M. Transition metal catalyzed intramolecular cyclizations of (trichloromethyl)alkenes [J]. Journal of Organic Chemistry 1990, 55(04).
[9] 何曼君, 陈维孝, 董西侠. 高分子物理 [M]. 上海:复旦大学出版社 1990.
[10] DESTARAC M, BESSIERE J M, BOUTERVIN B. Transition metal catalyzed atom transfer radical polymerization (ATRP): from heterogeneous to homogeneous catalysis using 1 10-phenantroline and its derivatives as new copper ligands [J]. Macromolecular Rapid Communications 1997, 18(11).
[11] 姚允斌, 解涛, 高英敏. 物理化学手册 [M]. 上海:上海科学技术出版社 1985.
