同轴式带孔内电极介质阻挡放电对聚丙烯和聚酯表面改性

  • 王赟 ,
  • 王伟伟 ,
  • 樊智慧 ,
  • 刘峰 ,
  • 师贵虎 ,
  • 王景全
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王赟(1997— ),男,河北工程大学在读硕士研究生,主要从事等离子体放电特性研究.E-mail: 1307696049@qq.com

收稿日期: 2024-01-03

  网络出版日期: 2025-02-25

基金资助

国家自然科学基金资助项目(11505045);河北省自然科学基金资助项目(A2012402002);邯郸市科学技术研究与发展计划项目(21422111227)

Surface modification of polypropylene and polyester by a coaxial perforated inner electrode dielectric barrier discharge

  • WANG Yun ,
  • WANG Weiwei ,
  • FAN Zhihui ,
  • LIU Feng ,
  • SHI Guihu ,
  • WANG Jingquan
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  • Hebei Computational Optical Imaging and Photoelectric Detection Technology Innovation Center, Hebei International Joint Research Center for Computational Optical Imaging and Intelligent Sensing, School of Mathematics and Physics, Hebei University of Engineering, Handan 056038, China

Received date: 2024-01-03

  Online published: 2025-02-25

摘要

为了提高等离子体对聚合物材料表面处理的应用效果,提出了一种同轴式带孔内电极介质阻挡放电反应器.实验结果表明:带孔内电极结构具有更高的放电功率,可在更短的时间内使接触角降的更低.该反应器产生等离子体对聚丙烯和聚酯表面改性,其表面接触角分别从90°降低到40°和从88°降低到30°.采用3种工作气体(氦气、氩气和空气),等离子体处理效果依次提高.该研究在工业应用中有着实用价值,为改善聚合物材料表面亲水性提供参考.

本文引用格式

王赟 , 王伟伟 , 樊智慧 , 刘峰 , 师贵虎 , 王景全 . 同轴式带孔内电极介质阻挡放电对聚丙烯和聚酯表面改性[J]. 河北大学学报(自然科学版), 2025 , 45(1) : 43 -49 . DOI: 10.3969/j.issn.1000-1565.2025.01.005

Abstract

In order to improve the application effect of plasma on the surface treatment of polymer materials, a coaxial perforated inner electrode dielectric barrier discharge reactor is proposed in this paper, and the experimental results show that the structure of the perforated inner electrode has higher discharge power, which can make the contact angle drop lower in a shorter period of time. The reactor generates plasma for surface modification of polypropylene and polyester, and the surface contact angle is reduced from 90° to 40° and from 88° to 30°, respectively. The effectiveness of the plasma treatment is increased by employing three working gases: helium, argon and air. This study has practical value in industrial applications and provides a reference for improving the surface hydrophilicity of polymer materials.

参考文献

[1] ZILLE A, OLIVEIRA F R, SOUTO A P. Plasma treatment in textile industry[J]. Plasma Process Polym, 2015, 12(2):98-131. DOI:10.1002/ppap. 201400052.
[2] HIMMA N F, ANISAH S, PRASETYA N, et al. Advances in preparation, modification, and application of polypropylene membrane[J]. J Polym Eng, 2016, 36(4):329-362. DOI:10. 1515/polyeng-2015-0112.
[3] FIGUEROA-PINOCHET M F, CASTRO-ALIJA M J, TIWARI B K, et al. Dielectric barrier discharge for solid food applications[J]. Nutrients, 2022, 14(21):4653. DOI:10.3390/nu14214653.
[4] JIN S, WANG S, ZHAO K, et al. A high-drive-performance microsecond pulse power module for portable DBD plasma source device[J]. IEEE Trans Power Electron, 2023. DOI:10.1109/TPEL.2023.3315524.
[5] DIMITRAKELLIS P, FAUBERT F, WARTEL M, et al. Plasma surface modification of epoxy polymer in air DBD and gliding arc[J]. Process, 2022, 10(1):104. DOI:10.3390/pr10010104.
[6] SHAKERINASAB E, SOHBATZADEH F. Surface modification of dielectric materials by Ar/toluene DBD plasma for flotation and drag reduction[J]. Appl Phys A, 2023, 129(12):1-19. DOI:10.1007/s00339-023-07121-y.
[7] SAWANGRAT C, THIPCHAI P, KAEWAPAI K, et al. Surface modification and mechanical properties improvement of bamboo fibers using dielectric barrier discharge plasma treatment[J]. Polym, 2023, 15(7):1711. DOI:10.3390/polym15071711.
[8] WARDANI A K, ARIONO D, SUBAGJO, et al. Hydrophilic modification of polypropylene ultr-afiltration membrane by airassisted polydopamine coating[J]. Polym Adv Technol, 2019, 30(4):1148-1155. DOI:10. 1002/pat. 4549.
[9] VAN DEYNSE A, DE GEYTER N, LEYS C, et al. Influence of water vapor addition on the surface modification of polyethylene in an argon dielectric barrier discharge[J]. Plasma Process Polym, 2014, 11(2):117-125. DOI:10. 1002/ppap. 201300088.
[10] LIU K, LEI J, ZHENG Z, et al. The hydrophilicity improvement of polytetrafluoroethylene by Ar plasma jet: The relationship of hydrophilicity, ambient humidity and plasma parameters[J]. Appl Surf Sci, 2018, 458:183-190. DOI:10. 1016/j. apsusc. 2018. 07. 061.
[11] KEHRER M, DUCHOSLAV J, HINTERREITER A, et al. Surface functionalization of polypropylene using a cold atmospheric pressure plasma jet with gas water mixtures[J]. Surf Coat Technol, 2020, 384:125170. DOI:10. 1016/j. surfcoat. 2019. 125170.
[12] YUAN H, WANG W, YANG D, et al. Hydrophilicity modification of aramid fiber using a linear shape plasma excited by nanosecond pulse[J]. Surf Coat Technol, 2018, 344:614-620. DOI:10.1016/j.surfcoat.2018.03.057.
[13] ZHU X, LI F, GUAN X, et al. Uniform-saturation modification for hydrophilicity improvement of large-scale PET by plasma-electrified treatment[J]. Eur Polym J, 2022, 181:111656. DOI:10.1016/j.eurpolymj.2022.111656.
[14] JIA P, JIA H, RAN J, et al. Efficient hydrophilicity improvement of titanium surface by plasma jet in micro-hollow cathode discharge geometry[J]. Chinese Phys B, 2023, 32(8):085202. DOI:10.1088/1674-1056/acbde9.
[15] 董丽芳,李树锋,刘富成,等.介质阻挡放电中气流对放电特性的影响[J].北京理工大学学报, 2005,(Suppl.1):8-10. DOI:10. 3969/j. issn. 1001-0645. 2005. z1. 003.
[16] 郝雅娟,董丽芳,刘富成,等.介质阻挡放电中放电丝的准粒子行为[J].河北大学学报(自然科学版), 2007, 27(1):28-31. DOI:10. 3969/j. issn. 1000-1565. 2007. 01. 010.
[17] LI X, LIU R, LI X, et al. Large-scale surface modification to improve hydrophilicity through using a plasma brush operated at one atmospheric pressure[J]. Phys Plasmas, 2019, 26(2): 023510. DOI:10.1063/1.5063328.
[18] WU J, WU K, CHEN J, et al. Influence of air addition on surface modification of polyethylene terephthalate treated by an atmospheric pressure argon plasma brush[J]. Plasma Sci Technol, 2021, 23(8):085504. DOI:10.1088/2058-6272/ac0109.
[19] ADAM N K. Use of the term ‘Young’s equation’ for contact angles[J].Nature, 1957, 180(4590):809-810. DOI:10. 1038/180809a0.
[20] LIU F, WANG Y, WANG W, et al. Generation of the high power by a coaxial dielectric barrier discharge with a perforated electrode in atmospheric pressure air[J]. Phys Plasmas, 2023, 30(9):093508. DOI:10.1063/5.0160137. (
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