Synthesis of a novel two dimensional BINOL metal-organic framework

doi:10.3969/j.issn.1000-1565.2018.05.007

Abstract

Abstract: 1,1'-binaphthyl-2,2'-dihydroxy-6,6'-dicarboxylic acid was synthesized from 2-hydroxy-6-naphthoic acid by esterification, coupling and hydrolysis. A new type of two-dimensional BINOL-Sr metal-organic framework(MOF(1))was synthesized by diffusion method. The complex crystalized in triclinic, P-1, with a = 0.787 5(4)nm, b = 1.242 1(8)nm, c = 1.336 4(9)nm,α= 114.64(2)°, β= 98.644(15)°,γ= 96.093(19)°, V = 1.153 8(13)nm³, Z = 2, R₁ = 0.049 6, wR₂ = 0.120 6.

Key words: 2-hydroxy-6-naphthoic acid, BINOL, crystal structure, MOFs.

CLC Number:

O62文献标志码:A

DONG Huanxin, LI Yiming, ZHAN Lei, LÜ Erpan, LI Lijun. Synthesis of a novel two dimensional BINOL metal-organic framework[J]. Journal of Hebei University (Natural Science Edition), 2018, 38(5): 490-495.

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