Journal of Hebei University(Natural Science Edition) >

2015 , Vol. 35 >Issue 1: 153

DOI: https://doi.org/１０．３９６９／ｊ．ｉｓｓｎ．１０００ １５６５．２０１５．０２．００８

A new Waugh molybdate formulated as (NH4)2(C5H6N)4MnMo9O32·8H2O has been isolated by reacting of (NH4)6MnMo9O32·6H2O and pyridine in aqueous solution, and characterized by single X-ray diffraction, elemental analysis, IR and solid UV-Vis diffuse reflectance spectroscopy. Crystal structural analysis indicate that the title compound crystallizes in the monoclinic system with space group P21/c, a = 2.1805(17) nm, b = 1.4394(11) nm, c = 1.5707(12) nm, β = 106.68(10)°, V = 4.7225(6) nm3, Z = 4, Dc = 3.386g cm-3, R1 = 0.0586, wR2 = 0.1831 (I>2 , GOF = 1.058.

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  • ＷＡＮＧＸｉａｏｆｅｉ ,
  • ＬＩＵＭａｎｆｅｉ ,
  • ＪＩＡＮＧＦａｎｇ
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Received date: 2014-09-25

  Online published: 2015-01-25

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ＬＩＵＸｕｅｍｅｉ , ＷＡＮＧＸｉａｏｆｅｉ , ＬＩＵＭａｎｆｅｉ , ＪＩＡＮＧＦａｎｇ . A new Waugh molybdate formulated as (NH4)2(C5H6N)4MnMo9O32·8H2O has been isolated by reacting of (NH4)6MnMo9O32·6H2O and pyridine in aqueous solution, and characterized by single X-ray diffraction, elemental analysis, IR and solid UV-Vis diffuse reflectance spectroscopy. Crystal structural analysis indicate that the title compound crystallizes in the monoclinic system with space group P21/c, a = 2.1805(17) nm, b = 1.4394(11) nm, c = 1.5707(12) nm, β = 106.68(10)°, V = 4.7225(6) nm3, Z = 4, Dc = 3.386g cm-3, R1 = 0.0586, wR2 = 0.1831 (I>2 , GOF = 1.058.[J]. Journal of Hebei University(Natural Science Edition), 2015 , 35(1) : 153 . DOI: １０．３９６９／ｊ．ｉｓｓｎ．１０００ １５６５．２０１５．０２．００８

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