The graft copolymerization of soluble starch was carried out using potassium diperiodatocuprate(Ⅲ) as the initiator in alkaline medium. It wa s found that Cu(Ⅲ)-starch system was an efficient redox initiator for the graf t copolymerization. The effect of initiator concentration, monomer concentration , reaction temperature on graft copolymerization was investigated. IR and therma lanalysis have determined the structure of the graft copolymer.
LIU Ying-hai
,
ZHANG Jin-song
,
LI Wei-ping
. Graft Copolymerization of Methyl Acrylate onto Soluble Starch Initiated with Potassium Diperiodatocuprate(Ⅲ)[J]. Journal of Hebei University(Natural Science Edition), 2001
, 21(1)
: 57
-60
.
DOI: 10.3969/j.issn.1000-1565.2001.01.014
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