Analysis of fluorescence process of DCM in solid matrix environment

  • XIE Ningbo ,
  • YIN Zhengzheng ,
  • DENG Ru ,
  • DANG Wei
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  • Hebei Key Laboratory of Optoeletronic Information Materials, College of Physics Science and Technology, Hebei University, Baoding 071002, China

Received date: 2019-05-29

  Online published: 2020-01-25

Abstract

Although DCM molecules are widely used in the field of lasers, organic light-emitting diodes, and etc., there are relatively few studies on its luminescence properties in solid matrices. In this paper DCM with 1% and 5%weight ratios were dissolved in poly(methyl methacrylate)(PMMA), and its emission process were analyzed at different temperatures. It was found that DCM sample(1% weight ratios)matrix polarity did not show significant change in temperature range of 295-35 K.However, DCM samples of 5%weight ratios, showed reduced matrix polarity in the temperature range of 295-195 K. Both DCM samples show fluorescence intensity and fluorescence lifetime increases with temperature decrease.

Cite this article

XIE Ningbo , YIN Zhengzheng , DENG Ru , DANG Wei . Analysis of fluorescence process of DCM in solid matrix environment[J]. Journal of Hebei University(Natural Science Edition), 2020 , 40(1) : 12 -17 . DOI: 10.3969/j.issn.1000-1565.2020.01.003

References

[1] DRAKE J M, LESIECKI M L, CAMAIONI D M. Photophysics and cis-trans isomerization of DCM[J]. Chem Phys Letters,1985,113(6):530-534.DOI: 10.1016/0009-2614(85)85026-0.
[2] MAMONOV E A, MAYDYKOVSKIY A I, MITETELO N V, et al. Whispering gallery modes in two-photon fluorescence fromspherical DCM dye microresonators[J]. Laser Physics Letters,2018, 15(3):1-5.DOI: 10.1088/1612-202X/aa9b23.
[3] KNA-COHENA S, STAVRINOU P N, BRADLEY D D C, et al.Random lasing in low molecular weight organic thin films[J]. Applied Physics Letters,2011,99(4): 041114 -041114-3.DOI:10.1063/1.3619169.
[4] MA C W, LENGYEL O, KOVAC J, et al. Time-resolved transient electroluminescence measurements of emission from DCM-doped Alq3 layers[J].Chemical Physics Letters,2004,397(1-3):87-90.DOI: 10.1016/j.cplett.2004.08.096.
[5] TANG C W, VANSLYKE S A, CHEN C H, et al. Electroluminescence of doped organic thin film [J].Journal of Applied physics,1989, 65( 9):3610-3616.DOI: 10.1063/1.343409.
[6] 刘彭义,赵福利,曹玲芳,等.DCM掺杂PVK体系的超快光谱[J]. 发光学报,2005,26(4):465-468.DOI: 10.3321/j.issn:1000-7032.2005.04.009.
[7] KUMAR S, PAL S K, MANDAL D, et al. Solvation dynamics of DCM in lipid[J].The Journal of Physical Chemistry B, 2000, 104(18): 4529-4531.DOI: 10.1021/jp993348t.
[8] MULDER C L, REUSSWIG P D, BEYLER A P, et al. Dye alignment in luminescent solar concentrators: II. Horizontal alignment for energy harvesting in linear polarizers[J]. Optics Express,2010,18(S1): A91-A99.DOI: 10.1364/OE.18.000A91.
[9] 李娟,李志强,田少华,等.温度对电致发光粉表面包覆 SiO2 膜特性的影响[J].河北大学学报(自然科学版),2004,24(1):32-35. DOI:1000-156(5 2004)01-0032-04.
[10] BONDAREV S L, KNYUKSHTO V N, STEPURO V I, et al. Fluorescence and Electronic Structure of the Laser Dye DCM in Solutions and in Polymethylmethacrylate[J]. Journal of Applied Spectroscopy,2004,2(71):194-201.DOI:0021-9037/04/7102-0194.
[11] 吕昆.DCM和罗丹明590激光染料发光动力学研究[D]. 哈尔滨: 哈尔滨工业大学,2011.
[12] BULOVIC V, DESHPANDE R, THOMPSON M E, et al. Tuning the color emission of thin film molecular organic light emitting devices by the solid state solvation effect[J].Chemical Physics Letters,1999,308(3-4):317-322.DOI:10.1016/s0009-2614(99)00580-1.
[13] BRUNO A, NENNA G, MAURO A, et al. Insight on photophysical proprieties of DCM dye in PVK host matrix[J]. Polymer Composites,2013,34(9):1500-1504.DOI:10.1002/pc.22441.
[14] 张洁,曹玲芳,陈丹,等.溶剂效应对DCM发光特性的影响[J]. 发光学报,2005,26(6):804-806.DOI:1000 7032(2005)06 0804 03.
[15] LUO Y C, AZIZ H, KLENKER R, et al. Temperature dependence of photoluminescence efficiency in doped andblended organic thin films[J]. Chemical Physics Letters,2008,458(4-6):319-322. DOI:10.1016/j.cplett.2008.05.007
[16] BERNARD V,BERBERAN-SANTOS M N. Molecular Fluorescence: Principles and Applications[M]. Beneficiary:Wiley-Vch Verlay Gmbh Isbns,2011527-60024-8(Electronic).
[17] CHANG C W,KAO Y T,DIAU W G, et al. Fluorescence lifetime and nonradiative relaxation dynamics of DCM in nonpolar solvent[J]. Chemical Physics Letters,2003, 374(1-2): 110-118.DOI: 10.1016/s0009-2614(03)00645-6.
[18] MARGUET S, MIALOCQ J C, MILLIE P, et al. Intramolecular charge transfer and trans-cis isomerization of the DCM styrene dye in polar solvents[J]. Chemical Physics,1992(160): 265-279.DOI: 10.1016/0301-0104(92)80127-h.
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