Measurement method and application of microwave photoconductivity in open cell mode

  • NIU Ben ,
  • TAO Tingting ,
  • HUANG Hao ,
  • WANG Tao ,
  • DANG Wei ,
  • DING Wenge
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  • College of Physics Science and Technology, Hebei University, Baoding 071002, China

Received date: 2021-04-29

  Online published: 2022-02-22

Abstract

Microwave photoconductivity technology can obtain the carrier recombination dynamic process of semiconductor materials, and provides a reference for the synthesis of semiconductor materials and the preparation of devices. In order to improve the accuracy of the microwave photoconductivity measurement system in open cell mode, influences of various experimental conditions, including excitation light energy, open circuit and short circuit conditions, distance between sample and short circuit end, excitation wavelength, were analyzed. The experimental results show that microwave photocunductance measurement in short circuit conditions can suppress the “oscillation” of photoconductance signal, when the sample thickness approximates with carrier diffusion length. Optimizing the distance between the sample and the short-circuit end can enhance the sensitivity of measurement. CH3NH3PbI3/PTAA(PTAA-polymer polytriarylamine)was characterized as a standard sample, and its hole transfer efficienies were about 84.1% and 59.1% after excitation by 532 nm and 355 nm, respectively. The results of this research are beneficial for the application of microwave photoconductivity technology in diagnoses of carrier recombination and interface charge transfer.

Cite this article

NIU Ben , TAO Tingting , HUANG Hao , WANG Tao , DANG Wei , DING Wenge . Measurement method and application of microwave photoconductivity in open cell mode[J]. Journal of Hebei University(Natural Science Edition), 2022 , 42(1) : 22 -28 . DOI: 10.3969/j.issn.1000-1565.2022.01.004

References

[1] LIU J,CHEN X L,WANG H G,et al. Study of surface photovoltage spectrum in p+-GaAs/p-GaAlAs/p-GaAs structures[J]. Materials Research Express, 2020, 7(9):096202. DOI: 10.1088/2053-1591/abb561.
[2] 高晓赫. CsFAMA三元阳离子钙钛矿薄膜载流子复合过程研究[D].保定:河北大学,2020. DOI: 10.27103/d.cnki.ghebu.2020.000948.
[3] SENGELE A,ROBERT D,KELLER N,et al. Sn-doped and porogen-modified TiO2 photocatalyst for solar light elimination of sulfure diethyle as a model for chemical warfare agent[J]. Applied Catalysis B: Environmental, 2019, 245:279-289. DOI:10.1016/j.apcatb.2018.12.071.
[4] STOLTZFUS D M,LARSON B W,ZARRABI N,et al.Investigating charge generation in polymer:non-fullerene acceptor bulk heterojunction films[J]. Organic Electronics, 2018, 55:177-186. DOI: 10.1016/j.orgel.2018.01.017.
[5] 尹政政,谢宁波,王凯,等.基于瞬态微波光电导测试仪的谐振腔传感器设计[J].光电子·激光,2019,30(10):1011-1016. DOI:10.16136/j.joel.2019.10.0086.
[6] 赵德浩. 基于基片集成波导技术的可调滤波器设计[D].西安:西安电子科技大学,2019. DOI:10.27389/d.cnki.gxadu.2019.002019.
[7] 闫润卿,李英惠.微波技术基础[M].3版.北京:北京理工大学出版社,2004:76-239.
[8] MALUTA E N N. Simulations of dye-sensitized solar cells [D].Bath:Philosophy University of Bath Department of Physics, 2010. DOI:10.1002/cssc.201100029.
[9] YANG Z B, YU Z H, WEI H T,et al. Enhancing electron diffusion length in narrow-bandgap perovskites for efficient monolithic perovskite tandem solar cells[J]. Nature Communications, 2019, 10:4498. DOI: 10.1038/s41467-019-12513-x.
[10] 陈凤翔,崔容强,徐林.微波光电导中的灵敏度分析[J].太阳能学报,2006,27(01):23-29.DOI:10.3321/j:issn:0254-0096.2006.01.005.
[11] INFELTA P P,DE HAAS M P,WARMAN J M. The study of the transient conductivity of pulse irradiated dielectric liquids on a nanosecond timescale using microwaves [J]. Radiation Physics & Chemistry, 1977, 10(5/6):353-365. DOI: 10.1016/0146-5724(77)90044-9.
[12] SCHÖFTHALER M, BRENDEL R. Sensitivity and transient response of microwave reflection measurements [J]. Journal of Applied Physics, 1995, 77(7):3162-3173. DOI:10.1063/1.358670.
[13] 陈文波.以PTAA为空穴传输层的倒置平面钙钛矿太阳能电池研究[D].哈尔滨:哈尔滨工业大学,2018. DOI: CNKI:CDMD:2.1018.893138.
[14] STRANKS S D,EPERON G E,GRANCINI G,et al. Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber[J]. Science,2013, 342(6156): 341-344. DOI: 10.1126/science.1243982.
[15] TIAN Y X,SCHEBLYKIN I G. Artifacts in absorption measurements of organometal halide perovskite materials: What are the real spectra?[J]. Journal of Physical Chemistry Letters,2015,6(17):3466-3470. DOI:10.1021/acs.jpclett.5b01406.
[16] ENDRES J,KULBAK M,ZHAO L F,et al. Electronic structure of the CsPbBr3/polytriarylamine(PTAA)system[J]. Journal of Applied Physics, 2017, 121(3):035304. DOI:10.1063/1.4974471. (
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