In order to achieve the comprehensive utilization of fly ash solid waste in recirculating fluidized bed and explore the alternative resources of bauxite, the dissolution of metal elements including aluminum, iron and titanium in circulating fluidized bed fly ash was studied by microwave digestion, sub-molten salt method and direct acid dissolution. Effects of different digestion conditions on the dissolution rate of various elements in fly ash were investigate and compared. The results showed that fly ash sample was digested by microwave method and the dissolution rate of aluminum element in fly ash was higher than 90% using 20% NaOH solution or HNO3-HCl-HF mixed acid as digestion solvent. The dissolution rates of titanium and iron were both less than 50% under alkaline conditions. Fly ash is difficult to dissolve by the sub molten salt method and acid method. But aluminum and iron were dissolved by acid leaching using the sub molten salt method. It provides a theoretical reference for the comprehensive utilization of circulating fluidized bed fly ash.
LIU Yanling
,
REN Yingqi
. Dissolution of metal elements in the circulating fluidized bed fly ash[J]. Journal of Hebei University(Natural Science Edition), 2022
, 42(1)
: 38
-43
.
DOI: 10.3969/j.issn.1000-1565.2022.01.006
[1] 王若超.粉煤灰高附加值绿色化综合利用的研究[D]. 沈阳:东北大学, 2013.
[2] 单雪媛.粉煤灰中有价元素分布规律及浸出行为研究[D]. 太原:山西大学, 2019.
[3] 王小芳.基于CFB粉煤灰提铝的铁杂质分离基础研究[D]. 太原:山西大学, 2020.
[4] 冯文丽,吕学斌,熊健,等.粉煤灰高附加值利用研究进展[J].无机盐工业, 2021, 53(4): 25-31. DOI:10.11962/1006-4990.2020-0284.
[5] GOLLAKOTA A R K, VOLLI V, SHU C M. Progressive utilisation prospects of coal fly ash: A review[J].The Science of the Total Environment, 2019, 672: 951-989. DOI:10.1016/j.scitotenv.2019.03.337.
[6] LI J, ZHUANG X G, QUEROL X, et al. Environmental geochemistry of the feed coals and their combustion by-products from two coal-fired power plants in xinjiang province, northwest China[J]. Fuel, 2012, 95: 446-456. DOI:10.1016/j.fuel.2011.10.025.
[7] DAI S F, ZHAO L, PENG S P, et al. Abundances and distribution of miner-als and elements in high-alumina coal fly ash from the jungar power plant, Inner Mongolia, China[J].International Journal of Coal Ge-ology, 2010, 81(4): 320-332. DOI:10.1016/j.coal.2009.03.005.
[8] VAN DYK J C, BENSON S A, LAUMB M L, et al. Coal and coal ash characteristics to understand mineral transformations and slag formation[J]. Fuel, 2009, 88(6): 1057-1063. DOI:10.1016/j.fuel.2008.11.034.
[9] CAO D Z, SELIC E, HERBELL J D. Utilization of fly ash from coal-fired power plants in China[J]. Journal of Zhejiang University-Science A, 2008, 9(5): 681-687. DOI: 10.1631/jzus.A072163.
[10] LIU Y X, ZENG F G, SUN B L, et al. Structural characterizations of aluminosilicates in two types of fly ash samples from Shanxi Province, North China[J]. Minerals, 2019, 9(6): 358. DOI:10.3390/min9060358.
[11] 胡小龙,陈炜,孙志娟,等.烧结-酸溶法从粉煤灰中溶出铝试验研究[J].湿法冶金, 2020, 39(1): 23-25. DOI:10.13355/j.cnki.sfyj.2020.01.005.
[12] 赵献辉,王浩宇,周博宇,等.粉煤灰基地聚物的性能影响因素及其凝胶产物研究进展[J].硅酸盐通报,2021,40(3):867-876. DOI:10.16552/j.cnki.issn1001-1625.2021.03.017.
[13] 易龙生,许元洪,赵立华,等. 粉煤灰基地质聚合物凝结时间的影响因素研究[J]. 矿冶工程,2020, 40(1): 114-117. DOI:10.3969/j.issn.0253-6099.2020.01.027.
[14] 王彬宇,李莉,李菁,等.用工业固体废料合成沸石分子筛的研究进展[J].高等学校化学学报, 2021, 42(1): 40-59. DOI:10.7503/cjcu20200362.
[15] 黄彩娟,符秀锋,徐本军.用粉煤灰制备分子筛工艺研究现状[J].湿法冶金, 2014, 33(1): 7-9. DOI:10.13355/j.cnki.sfyj.2014.01.003.
[16] 崔红梅,黄星,郭丹,等.粉煤灰在废水处理中的应用研究进展[J].化学通报,2020, 83(1): 35-41. DOI:10.14159/j.cnki.0441-3776.2020.01.021.
[17] 骆欣,杨怡心,徐东耀.热改性粉煤灰对水中Cu(Ⅱ)的吸附研究[J].应用化工,2020, 49(9): 2242-2245. DOI:10.16581/j.cnki.issn1671-3206.20200805.001.
[18] 丁健.高铝粉煤灰亚熔盐法提铝工艺应用基础研究[D].沈阳:东北大学, 2016. (