TiO2/SO42-催化季戊四醇双缩醛或双缩酮的合成

doi:10.3969/j.issn.1000-1565.2001.01.012

河北大学学报(自然科学版) ›› 2001, Vol. 21 ›› Issue (1): 49-52.DOI: 10.3969/j.issn.1000-1565.2001.01.012

TiO2/SO42-催化季戊四醇双缩醛或双缩酮的合成

孙旭¹,王晓凤²,靳通收¹,李同双¹

1.河北大学化学与环境科学学院； 2.河北省城乡建筑学校

出版日期:2001-02-25 发布日期:2001-02-25
基金资助:
国家自然科学基金，河北省教育厅科研项目

Synthesis of Diacetals from Aldehydes and Ketones with Pentaerythritol Catalysed by TiO2/SO42- Solid Superacid

SUN Xu¹,WANG Xiao-feng²,JIN Tong-Shou¹,LI Tong-shuang¹

Online:2001-02-25 Published:2001-02-25

摘要/Abstract

摘要： 在固体超强酸 TiO2/SO42-催化下，以苯或甲苯为脱水剂，季戊四醇与醛、酮反应，制得了产率为85%～97%的双缩醛或双缩酮.

关键词: 固体超强酸, 季戊四醇, 双缩醛

Abstract: Synthesis of diacetals in 85%～97% yields from aldehydes and ketones with 2,2-bis(hydroxymethyl)propane-1,3-diol is carried out in refluxin g benzene or toluene with TiO2/SO42- solid superacid as catalyst.

中图分类号:

O621.54

孙旭,王晓凤,靳通收,李同双. TiO2/SO42-催化季戊四醇双缩醛或双缩酮的合成[J]. 河北大学学报(自然科学版), 2001, 21(1): 49-52.

SUN Xu,WANG Xiao-feng,JIN Tong-Shou,LI Tong-shuang. Synthesis of Diacetals from Aldehydes and Ketones with Pentaerythritol Catalysed by TiO2/SO42- Solid Superacid[J]. Journal of Hebei University (Natural Science Edition), 2001, 21(1): 49-52.

参考文献

[1] KLYUSHNIK N P. Condensation of pentaerythritol with cyclohexanone and of ethylene glycol with cyclohexanedione [J]. Ukrainskii Khimicheskii Zhurnal 1964, 30(09).
[2] CALLOJAS D, ECHENIQUE M, SEEBOTH H. Reaction of furfural and 5-n itrofurfural with pentaerythritol [J]. Rev Cubana Quim 1998, 4(01).
[3] MKHITARYAN V G. Catalytic effect of p-toluenesulfonic acid on the reaction of acetals with pentaerythritol [J]. Journal of General Chemistry of the USSR 1939, 9(09).
[4] BACKER H J, SCHURINK H B. The reaction of pentaerythritol with aldehyd es under the influence of zinc chloride [J]. Rec Erav Chim 1931, 50.
[5] ORTHNER L. Acetone compounds of pentaerythritol(preliminary) commu nication [J]. Chemische Berichte 1928, 61.
[6] SHAKHTAKHTINSKII T N, ANDREEY L V. Condensation of pentaerythrito l with ca rbonyl compounds in the presence of cation exchanger KU-2 [J]. Akad Nauk Azerb 1962, 18(12).
[7] 陈新, 徐永廷, 金春霞. 季戊四醇双缩醛的合成与表征 [J]. 1997.
[8] Zhang Z H, LI T S, JIN T S. Montmorillonite clays cataly sis. Part 12.1 An efficient and practical procedure for synthesis of diacetals from 2, 2-bi s(hydroxymethyl)-1, 3-propanediol with carbonyl compounds [J]. Journal of Chemical Research 1998.
[9] Tong-Shou Jin, Tong-Shuang Li, Zhan-Hui Zhang, Yan-Jun Yuan. Synthesis of diacetals by condensation of carbonyl compounds with bis(hydroxymethyl)-1, 3-propanediol catalysed by expansive graphite [J]. Synthetic Communications 1999, 9(9).
[10] JIN T S, MA Y R, Li T S. A practical and efficient procedu re for pr eparation of diacetals from 2, 2- bis(hydroxymethyl) propane -1, 3-diol with aldeh ydes and ketones catalysed by anhydrous ferrous sulfate [J]. Journal of Chemical Research 1999.
[11] Hino M, KAZUSHI A. Reaction of butane and isobutane catalysed by titanium oxide treated with sulphate ion. solid superacid catalyst [J]. Journal of the Chemical Society, Chemical Communications 1979.
[12] Wang CD., Xie RJ., Shi XZ.. SYNTHESIS OF DIACETALS OF 2, 2-BIS(HYDROXYMETHYL)-1, 3-PROPANEDIOL UNDER MICROWAVE IRRADIATION [J]. Synthetic Communications 1997, 14(14).

TiO2/SO42-催化季戊四醇双缩醛或双缩酮的合成

Synthesis of Diacetals from Aldehydes and Ketones with Pentaerythritol Catalysed by TiO2/SO42- Solid Superacid

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 5

编辑推荐

Metrics

本文评价

[1]	马志领,李晓英,丁春月. 季戊四醇醚化氨基树脂为基材的膨胀型防火清漆[J]. 河北大学学报(自然科学版), 2013, 33(1): 29-34.
[2]	白国义,石敏瑜,韩捷,高大民. 单、双季戊四醇联产工艺的优化[J]. 河北大学学报(自然科学版), 2011, 31(4): 376-379.
[3]	靳通收,冯国良,杨米娜,李同双. 微波辐射下ZrO2/S2O82-催化合成芳香磺酰亚胺[J]. 河北大学学报(自然科学版), 2004, 24(3): 258-262.
[4]	张素玲,靳通收,刘卉闵,郭俊杰,李同双. ZrO2/SO2-4类固体超强酸在有机合成中的应用进展[J]. 河北大学学报(自然科学版), 2001, 21(4): 448-454.
[5]	马志领,宋占表,胡汉芳,牛海军,白雪. 膨胀型阻燃剂的膨胀效果和应用于聚丙烯的阻燃效果[J]. 河北大学学报(自然科学版), 2001, 21(2): 138-141.