过渡金属超常氧化态配离子的存在形式

doi:10.3969/j.issn.1000-1565.2004.03.024

摘要/Abstract

摘要： 对晶体和碱性介质中过渡金属超常氧化态配离子的主要存在形式和反应活化中心进行了综述,参考文献63篇.基于对过渡金属超常氧化态配离子氧化某些复杂的有机化合物的研究,提出了以低质子化程度的配离子作为反应活化中心的假设,该假设得到笔者的计算、实验结果的支持,从而否定了印度学者提出的以高质子化程度的配离子作为活化中心的假设.

中图分类号:

O641.4

王立平,单金缓,孙汉文. 过渡金属超常氧化态配离子的存在形式[J]. 河北大学学报(自然科学版), 2004, 24(3): 320-325.

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过渡金属超常氧化态配离子的存在形式

Existence of Transition Metals in Highest Oxidation State Complex

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