锁磷剂对府河底泥磷释放的影响

doi:10.3969/j.issn.1000-1565.2018.04.009

河北大学学报(自然科学版) ›› 2018, Vol. 38 ›› Issue (4): 396-402.DOI: 10.3969/j.issn.1000-1565.2018.04.009

锁磷剂对府河底泥磷释放的影响

王军霞¹,张亚娟¹,张蕾¹,王亚斌²,刘存歧¹

收稿日期:2017-12-20 出版日期:2018-07-25 发布日期:2018-07-25
通讯作者: 刘存歧(1967—),男,河北昌黎人,河北大学教授,主要从事湿地生态学研究.E-mail: liucunqi@sina.com
作者简介:王军霞(1974—),女,河北新乐人,河北大学副教授,主要从事水域生态学研究. E-mail: wangjun_xia@sohu.com
基金资助:
国家水体污染控制与治理科技重大水专项(2012zx07203)

Impacts of phoslock on sediment phosphorus release in Fuhe River

WANG Junxia¹, ZHANG Yajuan¹,ZHANG Lei¹, WANG Yabin², LIU Cunqi¹

1.College of Life Science, Hebei University, Baoding 071002, China; 2.Environmental Monitoring Centre of Baoding, Baoding 071000, China

Received:2017-12-20 Online:2018-07-25 Published:2018-07-25

摘要/Abstract

摘要： 选用美国新一代锁磷剂SAE,进行了45 、90 、180 g/m² 3种不同剂量的锁磷剂控制府河底泥磷释放的模拟实验研究.结果表明,SAE降低了府河河道底泥上覆水中的总磷(TP)、可溶性正磷酸盐(SRP)、可溶性总磷酸盐(DTP)含量,添加90 g/m²和180 g/m² SAE的抑磷率达到80%以上且效果稳定. 底泥中向上覆水释放的磷主要来自于可交换态磷(Ex-P)和铁铝结合态磷(NaOH-P),钙结合态磷(HCl-P)含量变化不显著,SAE的添加使得底泥中的磷形态发生了转变,Ex-P 和NaOH-P向HCl-P转化,使得稳定态磷占比增大,降低了沉积物磷向上覆水释放的风险.

关键词: 锁磷剂, 沉积物, 磷释放

Abstract: An experimental study on controlling the release of phosphorus from Fuhe river sediments using a new generation of phosphorus control agent SAE from US were conducted. The results showed that the concentrations of total phosphorus(TP), dissolved total phosphorus(DTP)and dissolved inorganic phosphorus(SRP)in overlying water of sediment decreased. With SAE added at 90 g/m² and 180 g/m², sediment phosphate release suppression efficiency reached 80%. Exchangeable phosphorus(Ex-P)and iron aluminum bound phosphorus(NaOH-P)were found to have the greatest potential of the phosphorus release. Calcium bound phoaphorus(HCl-P)content remained unchanged. When the phoslock SAE was added, the content of Ex-P and NaOH-P decreased, the content of HCl-P increased. Phoslock SAE changed the more easily released form of phosphorus into the more stable form. The risk of phosphorus released could be effectively reduced.

Key words: phoslock, sediment, phosphorus release

中图分类号:

王军霞,张亚娟,张蕾,王亚斌,刘存歧. 锁磷剂对府河底泥磷释放的影响[J]. 河北大学学报(自然科学版), 2018, 38(4): 396-402.

WANG Junxia, ZHANG Yajuan,ZHANG Lei, WANG Yabin, LIU Cunqi. Impacts of phoslock on sediment phosphorus release in Fuhe River[J]. Journal of Hebei University (Natural Science Edition), 2018, 38(4): 396-402.

参考文献

[1] 边蔚,田在锋,李楠,等. 滏阳河衡水市区段沉积物硝酸盐氮的扩散规律[J].河北大学学报(自然科学版),2016,36(3):269-277.DOI:10.3969/j.issn. 1000-1565.2016. 03.009. BIAN W, TIAN Z F, LI N, et al. Diffusion of nitrate nitrogen in sediment of stream segment of Fuyang River through Hengshui City[J]. Journal of Hebei University(Natural Science Edition), 2016, 36(3): 269-277.DOI:10.3969/j.issn.1000-1565.2016. 03.009.
[2] 杨永琼, 陈敬安, 王敬富, 等. 沉积物磷原位钝化技术研究进展[J]. 地球科学进展, 2013, 28(6): 674-683. YANG Y Q, CHEN J A, WANG J F, et al. Research progress of sediments phosphorus in-situ inactivation[J]. Advances in Earth Science, 2013, 28(6): 674-683.
[3] 亢增军, 袁林江, 孔海霞. 3种覆盖材料对底泥磷释放的抑制及影响因素研究[J]. 安全与环境学报, 2014, 14(3): 202-205. DOI:10.13637/ j.issn.1009-6094.2014.03.045. KANG Z J, YUAN L J, KONG H X. Inhibiting effect of the three kinds of barriers on the release of sediment phosphorus and the influential factors[J]. Journal of Safety and Environment, 2014, 14(3): 202-205. DOI:10.13637/j.issn.1009-6094.2014. 03.045.
[4] ROBB M, GREENOP B, GOSS Z, et al. Application of phoslock^TM, an innovative phosphorns binding clay, to two Western Australian waterways: preliminary findings[J]. Hydrobiologia, 2003,494(1-3): 237-243. DOI: 10.1023/A:1025478618611.
[5] 陈小燕, 刘键熙, 苏玉萍, 等. 两种锁磷剂锁磷效果对比研究[J]. 福建师范大学学报, 2016, 32(4): 56-60. CHEN X Y, LIU J X, SU Y P, et al. Study on effect of adsorption comparative of two kinds of phosphorus locking agent[J]. Journal of Fujian Normal University, 2016, 32(4): 56-60.
[6] 国家环境保护总局.水和废水监测分析方法[M]. 第4版.北京: 中国环境科学出版社, 2002:243-250.
[7] 韩璐, 黄岁樑, 王乙震. 海河干流柱芯不同粒径沉积物中有机质和磷形态分布研究[J]. 农业环境科学学报, 2010,29(5): 955-962. HAN L, HUANG S L, WANG Y Z. Organic matter, different sized phosphorus fractions in the core sediments in the mainstream of Haihe River, China[J]. Journal of Agro-Environment Science, 2010,29(5):955-962.
[8] 梁英, 王帅, 冯力震, 等. 重金属胁迫对纤细角毛藻生长及叶绿素荧光特性的影响[J]. 中国海洋大学学报, 2008,38(1):59-67. LIANG Y, WANG S, FENG L Z, et al. Effects of heavy metal stress on the growth and chlorophy fluorescence of Chaetoceros gracilis[J]. Periodical of Ocean University of China, 2008, 28(1): 59-67.
[9] 孙淑娟, 黄岁樑. 海河沉积物中磷释放的模拟研究[J]. 环境科学研究, 2008, 21(4): 126-131. DOI:10.13198/j.res.2008. 04.128.sunshj.022. SUN S J, HUANG S L. Simulated experiment of phosphorus release from Haihe River sediment[J]. Research of Environmental Sciences, 2008, 21(4): 126-131. DOI:10.13198/j.res.2008. 04.128.sunshj.022.
[10] 杨洁, 刘波, 常素云, 等. 富营养化水体原位控磷技术研究及应用[J].水资源保护, 2013, 29(2): 10-17.DOI:10.3969 / j. issn. 1004-6933. 2013. 02.003. YANG J, LIU B, CHANG S Y, et al. Research and application of in situ phosphorus control technology in eutrophic water bodies[J]. Water Resources Protection, 2013, 29(2): 10-17. DOI:10.3969 / j. issn. 1004-6933. 2013. 02.003.
[11] 苏玉萍, 张超伟, 龚建, 等. 锁磷剂调控富营养化水体沉积物磷污染实验研究[J]. 福建师范大学学报, 2015, 31(6): 48-54. SU Y P, ZHANG, C W, GONG J, et al. Experimental study on controlling release of phosphorus from eutrophic water sediments using phosphorus binding agent[J]. Journal of Fujian Normal University, 2015, 31(6): 48-54.
[12] 薛巍, 卢少勇. 低温下不同钝化剂抑制底泥磷释放的性能研究[J]. 环境科学与技术, 2015, 38(3): 54-60.DOI:10.3969/j. issn.1003-6504.2015.03.011. XU W, LU S Y. Effect of different inactivation agents on the phosphorus release at hypothermy[J]. Environmental Science & Technolgy, 2015, 38(3): 54-60. DOI:10.3969/j.issn.1003-6504.2015.03.011.
[13] 朱广伟, 李静, 朱梦圆, 等. 锁磷剂对杭州西湖底泥磷释放的控制效果[J].环境科学, 2017, 38(4): 1451-1459.DOI:10. 13227 /j.hjkx.201609123. ZHU G W, LI J, ZHU M Y, et al. Efficacy of phoslock on the reduction of sediment phosphorus release in West Lake, Hangzhou, China[J]. Environmental Science, 2017, 38(4): 1451-1459. DOI: 10. 13227 /j.hjkx.201609123.
[14] 林娟, 邱佩璜, 范华, 等. 原位化学处理对沉积物-水系统氮磷影响研究[J].环境科学与技术, 2016, 39(s2): 271-276. DOI:10.3969/j.issn.1003-6504.2016.S2.053. LIN J, QIU P H, FAN H, et al. Effects of in-situ chemical remediation on phosphorus and nitrogen in sediment-water system[J]. Environmental Science & Technology, 2016, 38(s2): 271-276. DOI:10.3969/j.issn.1003-6504.2016.S2.053.
[15] 李静, 朱广伟, 张晓松, 等. 锁磷剂及覆盖技术对长广溪不同污染类型河段底泥磷释放的控制效果[J].环境化学, 2015,34(2):358-366. DOI: 10.7524 / j.issn.0254-6108.2015.02.2014061609. LI J, ZHU G W, ZHANG X S, et al. Control effect of phoslock and sand-capping on sediment phosphorus release in different polluted sections of Changguangxi River[J]. Environmental Chemistry, 2015, 34(2): 358-366.DOI:10.7524/j.issn. 0254-6108.2015.02.2014061609.
[16] 王秀朵, 张大群, 刘瑶, 等. 锁磷剂用于富营养化水体除磷的研究[J].中国给水排水, 2010, 26(23): 88-90. WANG X D, ZHANG D Q, LIU Y, et al. Study on removal of phosphorus from eutrophic water using phoslock[J]. China Water & Wastewater, 2010, 26(23): 88-90.
[17] ROSS G, HAGHSERESHT F, GLOETE T. The effect of pH and anoxia on the performance of Phoslock, a phosphorus binding clay[J]. Harmful Algae, 2008, 7(4): 545-550. DOI:10.1016/j.hal.2007.12.007.
[18] 吴涛. 锁磷剂在富营养化水体中的应用研究[D]. 天津: 天津大学建筑工程学院, 2012: 23-27. WU T. Research on the application of phoslock on the eutrophication waters[D]. Tianjin: Tianjin Jianzhu Engineering College, 2012: 23-27.
[19] LÜRLING M, OOSTERHOUT F. Case study on the efficacy of a lanthanum-enriched clay(Phoslock)in controlling eutrophication in Lake Het Groene Eiland(The Netherlands)[J].Hydrobiology, 2012, 710(1):253-263.DOI: 10.1007/s 10750-012-1141-x.
[20] 王华光, 王凌燕, 王文静, 等. 锁磷剂对流动水环境中沉积物磷形态的作用[J].环境污染与防治, 2015, 37(11):41-46. DOI:10.15985/j.cnki.1001-3865.2015.11.008. WANG H G, WANG L Y, WANG W J, et al. Effect of phoslock on the phosphorus forms in sediments with fluxion water condition[J]. Environmental Pollution & Control, 2015,37(11):41-46. DOI:10.15985/j.cnki.1001-3865.2015. 11.008.

锁磷剂对府河底泥磷释放的影响

Impacts of phoslock on sediment phosphorus release in Fuhe River

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