一种新型二维BINOL金属-有机框架的合成

doi:10.3969/j.issn.1000-1565.2018.05.007

河北大学学报(自然科学版) ›› 2018, Vol. 38 ›› Issue (5): 490-495.DOI: 10.3969/j.issn.1000-1565.2018.05.007

一种新型二维BINOL金属-有机框架的合成

董焕新^1,2,李一鸣¹,詹磊²,吕二盼²,李立军¹

收稿日期:2018-03-07 出版日期:2018-09-25 发布日期:2018-09-25
通讯作者: 李立军(1969-),男,河北定州人,河北大学教授,博士,主要从事有机合成与配合物研究. E-mail: llj@hbu.edu.cn
作者简介:董焕新(1987-),男,河北曲阳人,河北大学在读硕士研究生, 主要从事配位聚合物研究. E-mail: 63382027@qq.com
基金资助:
河北省自然科学基金资助项目(B2014201174)

Synthesis of a novel two dimensional BINOL metal-organic framework

DONG Huanxin^1,2, LI Yiming¹, ZHAN Lei², LÜ Erpan², LI Lijun¹

1. Key Laboratory of Chemical Biology of Hebei Province, College of Chemistry and Environmental Science, Hebei University, Baoding 071002, China; 2. Baoding Products Quality Supervision and Inspection Institute, Baoding 071000, China

Received:2018-03-07 Online:2018-09-25 Published:2018-09-25

摘要/Abstract

摘要： 以2-羟基-6-萘甲酸为原料,经过酯化、偶合、水解制得配体1,1'-联萘-2,2'-二羟基-6,6'-二甲酸,并以扩散法合成了一种新型二维BINOL-Sr金属有机框架(MOF(1)). 配合物为三斜晶系,P-1空间群,晶胞参数:a=0.787 5(4)nm, b=1.242 1(8)nm, c=1.336 4(9)nm, α=114.64(2)°, β=98.644(15)°, γ=96.093(19)°, V=1.153 8(13)nm³, Z=2, R₁=0.049 6, wR₂=0.120 6.

关键词: 2-羟基-6-萘甲酸, BINOL, 晶体结构, MOFs.

Abstract: 1,1'-binaphthyl-2,2'-dihydroxy-6,6'-dicarboxylic acid was synthesized from 2-hydroxy-6-naphthoic acid by esterification, coupling and hydrolysis. A new type of two-dimensional BINOL-Sr metal-organic framework(MOF(1))was synthesized by diffusion method. The complex crystalized in triclinic, P-1, with a = 0.787 5(4)nm, b = 1.242 1(8)nm, c = 1.336 4(9)nm,α= 114.64(2)°, β= 98.644(15)°,γ= 96.093(19)°, V = 1.153 8(13)nm³, Z = 2, R₁ = 0.049 6, wR₂ = 0.120 6.

Key words: 2-hydroxy-6-naphthoic acid, BINOL, crystal structure, MOFs.

中图分类号:

O62文献标志码:A

董焕新,李一鸣,詹磊,吕二盼,李立军. 一种新型二维BINOL金属-有机框架的合成[J]. 河北大学学报(自然科学版), 2018, 38(5): 490-495.

DONG Huanxin, LI Yiming, ZHAN Lei, LÜ Erpan, LI Lijun. Synthesis of a novel two dimensional BINOL metal-organic framework[J]. Journal of Hebei University (Natural Science Edition), 2018, 38(5): 490-495.

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一种新型二维BINOL金属-有机框架的合成

Synthesis of a novel two dimensional BINOL metal-organic framework

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