TiO2/SO42-催化季戊四醇双缩醛或双缩酮的合成

  • 孙旭 ,
  • 王晓凤 ,
  • 靳通收 ,
  • 李同双
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  • 1.河北大学 化学与环境科学学院; 2.河北省城乡建筑学校

网络出版日期: 2001-02-25

基金资助

国家自然科学基金,河北省教育厅科研项目

Synthesis of Diacetals from Aldehydes and Ketones with Pentaerythritol Catalysed by TiO2/SO42- Solid Superacid

  • SUN Xu ,
  • WANG Xiao-feng ,
  • JIN Tong-Shou ,
  • LI Tong-shuang
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Online published: 2001-02-25

摘要

在固体超强酸 TiO2/SO42-催化下,以苯或甲苯为脱水 剂,季戊四醇与醛、酮反应,制得了产率为85%~97%的双缩醛或双缩酮.

本文引用格式

孙旭 , 王晓凤 , 靳通收 , 李同双 . TiO2/SO42-催化季戊四醇双缩醛或双缩酮的合成[J]. 河北大学学报(自然科学版), 2001 , 21(1) : 49 -52 . DOI: 10.3969/j.issn.1000-1565.2001.01.012

Abstract

Synthesis of diacetals in 85%~97% yields from aldehydes and ketones with 2,2-bis(hydroxymethyl)propane-1,3-diol is carried out in refluxin g benzene or toluene with TiO2/SO42- solid superacid as catalyst.

参考文献

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