以2-羟基-6-萘甲酸为原料,经过酯化、偶合、水解制得配体1,1'-联萘-2,2'-二羟基-6,6'-二甲酸,并以扩散法合成了一种新型二维BINOL-Sr金属有机框架(MOF(1)). 配合物为三斜晶系,P-1空间群,晶胞参数:a=0.787 5(4)nm, b=1.242 1(8)nm, c=1.336 4(9)nm, α=114.64(2)°, β=98.644(15)°, γ=96.093(19)°, V=1.153 8(13)nm3, Z=2, R1=0.049 6, wR2=0.120 6.
1,1'-binaphthyl-2,2'-dihydroxy-6,6'-dicarboxylic acid was synthesized from 2-hydroxy-6-naphthoic acid by esterification, coupling and hydrolysis. A new type of two-dimensional BINOL-Sr metal-organic framework(MOF(1))was synthesized by diffusion method. The complex crystalized in triclinic, P-1, with a = 0.787 5(4)nm, b = 1.242 1(8)nm, c = 1.336 4(9)nm,α= 114.64(2)°, β= 98.644(15)°,γ= 96.093(19)°, V = 1.153 8(13)nm3, Z = 2, R1 = 0.049 6, wR2 = 0.120 6.
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