量子点敏化太阳能电池研究进展

李玲; 马泽元; 李紫祥; 魏爱超; 李帆; 章忆康; 赵亚军

doi:10.3969/j.issn.1000-1565.2020.05.004

河北大学学报(自然科学版) >

2020 , Vol. 40 >Issue 5: 469 - 476

DOI: https://doi.org/10.3969/j.issn.1000-1565.2020.05.004

量子点敏化太阳能电池研究进展

李玲 ,
马泽元 ,
李紫祥 ,
魏爱超 ,
李帆 ,
章忆康 ,
赵亚军

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李玲(1980—),女,河北保定人,河北大学教授,主要从事多功能纳米材料与光电器件的研究. E-mail:lilinghbu@163.com

收稿日期: 2020-05-01

网络出版日期: 2020-09-25

基金资助

河北大学2020年大学生创新创业计划训练项目(2020221;2020223;2020226;2020227)

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Research progress of quantum dot-sentitized solar cells

LI Ling ,
MA Zeyuan ,
LI Zixiang ,
WEI Aichao ,
LI Fan ,
ZHANG Yikang ,
ZHAO Yajun

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National-Local Joint Engineering Laboratory of New Energy Photoelectric Devices, Hebei Key Lab of Optic-electronic Information and Materials, College of Physics Science and Technology, Hebei University, Baoding 071002, China

Received date: 2020-05-01

Online published: 2020-09-25

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摘要

量子点敏化太阳能电池因其优点众多(如制备工艺简单、成本低以及理论光电转换效率高等)而备受关注,目前最高效率已经突破13%.而电池性能的优劣主要由光阳极、对电极以及电解质共同决定,本文从以上几部分入手并简要阐述了量子点敏化太阳能电池由哪些重要部分构成、对外电路工作的内部反应机制和各重要部件当前的探索现状,着重综述了光阳极当前的研究成果以及存在的问题,并对光阳极的优化途径进行了展望.

关键词： 量子点敏化太阳能电池; 光阳极; 量子点敏化剂; 半导体氧化物

本文引用格式

李玲 , 马泽元 , 李紫祥 , 魏爱超 , 李帆 , 章忆康 , 赵亚军 . 量子点敏化太阳能电池研究进展[J]. 河北大学学报(自然科学版), 2020 , 40(5) : 469 -476 . DOI: 10.3969/j.issn.1000-1565.2020.05.004

Abstract

Quantum dots sensitized solar cells have received much attention because of its many advantages(such as straight forward synthesis procedure, low spending and superior theoretical photoelectric conversion property), the highest efficiency has exceeded 13%.The performance of the solar cell is mainly caused by the photoanode, the counter electrode and the electrolyte. Therefore, optimizing the above parts can greatly improve the cells performance. This paper introduces the structure, working principle and the latest research progress of quantum dot sensitized solar cells. The current research results and existing problems of photoanodes are reviewed, and the optimization of photoanodes is further prospected.

Key words： quantum dot sensitized solar cells; photoanodes; quantum dot sensitizers; semiconductor oxides

参考文献

[1] LOHSE S E, MURPHY C J. Applications of colloidal inorganic nanoparticles: from medicine to energy[J]. Journal of the American Chemical Society, 2012, 134(38):15607-15620. DOI:10.1021/ja307589n.
[2] HOERTZ P G, STANISZEWSKI A, MARTON A, et al. Toward exceeding the shockley-queisser limit: photoinduced interfacial charge transfer processes that store energy in excess of the equilibrated excited state[J]. Journal of the American Chemical Society, 2006, 128(25):8234-8245. DOI:10.1021/ja060470e.
[3] NOZIK A J, BEARD M C, LUTHER J M, et al. Semiconductor quantum dots and quantum dot arrays and applications of multiple exciton generation to third-generation photovoltaic solar cells[J]. Chemical Reviews, 2010, 110(11):6873-6890. DOI: 10.1021/cr900289f.
[4] SHEN K, LUO G, LIU J, et al. Highly transparent photoelectrochromic device based on carbon quantum dots sensitized photoanode[J]. Solar Energy Materials and Solar Cells, 2019, 1(193):372-378. DOI:10.1016/j.solmat.2019.01.004.
[5] SAMBUR J B, NOVET T, PARKINSON B A. Multiple exciton collection in a sensitized photovoltaic system[J]. Science, 2010, 330(6000):63-66. DOI:10.1126/science.1191462.
[6] LI Z, YU L, WANG H, et al. TiO₂ passivation layer on ZnO hollow microspheres for quantum dots sensitized solar cells with improved light harvesting and electron collection[J]. Nanomaterials, 2020, 10(4):631. DOI:10.3390/nano10040631.
[7] POLMAN A, ATWATER H A. Photonic design principles for ultrahigh-efficiency photovoltaics[J]. Nature Materials, 2012, 11(3):174-177. DOI:10.1038/nmat3263.
[8] HOD I, ZABAN A. Materials and interfaces in quantum dot sensitized solar cells: challenges, advances and prospects[J]. Langmuir, 2014, 30(25):7264-7273. DOI:10.1021/la403768j.
[9] NOZIK A. Quantum dot solar cells[J]. Physica E:Low-Dimensional Syst Nanostructures, 2002, 14(1-2):115-120. DOI:10.1016/S1386-9477(02)00374-0.
[10] LEE Y L, LO Y S. Highly efficient quantum-dot-sensitized solar cell based on co-sensitization of CdS/CdSe[J]. Advanced Functional Materials, 2009, 19(4):604-609. DOI:10.1002/adfm.200800940.
[11] YUAN B, GAO Q, ZHANG X, et al. Reduced graphene oxide(RGO)/Cu₂S composite as catalytic counter electrode for quantum dot-sensitized solar cells[J]. Electrochimica Acta, 2018, 1(277):50-58. DOI:10.1016/j.electacta.2018.04.218.
[12] PAN Z, YUE L, RAO H, et al. Boosting the performance of environmentally friendly quantum dot-sensitized solar cells over 13% efficiency by dual sensitizers with cascade energy structure[J]. Advanced Materials, 2019, 31(49):1903696. DOI: 10.1002/adma.201903696.
[13] CHANDIRAN A K, ABDI-JALEBI M, NAZEERUDDIN M K, et al. Analysis of electron transfer properties of ZnO and TiO₂ photoanodes for dye-sensitized solar cells[J]. ACS Nano, 2014, 8(3):2261-2268. DOI: 10.1021/nn405535j.
[14] LU Y, JIA J, LU C, et al. Enhancing the photoelectrochemical properties of quantum dot-sensitized solar cells based on TiO₂ nanorods by using fast hole transfer channels[J]. Materials Letters, 2019, 15(243):176-179. DOI:10.1016/j.matlet.2019.01.110.
[15] HUANG K Y, LUO Y H, CHENG H M, et al. Performance enhancement of CdS/CdSe quantum dot-sensitized solar cells with(001)-oriented anatase TiO₂ nanosheets photoanode[J]. Nanoscale Research Letters, 2019, 14(1):18. DOI:10.1186/s11671-018-2842-5.
[16] SHEN W, ZHANG J, WANG S, et al. Improve the performance of the quantum dot sensitized ZnO nanotube solar cells with inserting ZnS-MnS composites layers[J]. Journal of Alloys and Compounds, 2019, 787:751-758. DOI:10.1016/j.jallcom.2019.02.108.
[17] AHMED R, WILL G, BELL J, et al. Size-dependent photodegradation of CdS particles deposited onto TiO₂ mesoporous films by SILAR method[J]. Journal of Nanoparticle Research, 2012, 14(9):1140. DOI:10.1007/s11051-012-1140-x.
[18] BUATONG N, TANG I M, PON-ON W. Quantum dot-sensitized solar cells having 3D-TiO₂ flower-like structures on the surface of titania nanorods with CuS counter electrode[J]. Nanoscale Research Letters, 2015, 10(1):1-10. DOI:10.1186/s11671-015-0844-0.
[19] SANTRA P K, KAMAT P V. Mn-doped quantum dot sensitized solar cells: a strategy to boost efficiency over 5%[J]. Journal of the American Chemical Society, 2012, 134(5):2508-2511. DOI:10.1021/ja211224s.
[20] DE LA FUENTE M S, SÁNCHEZ R S, GONZÁLEZ-PEDRO V, et al. Effect of organic and inorganic passivation in quantum-dot-sensitized solar cells[J]. The Journal of Physical Chemistry Letters, 2013, 4(9):1519-1525. DOI: 10.1021/jz400626r.
[21] GOPI C V V M, VENKATA-HARITHA M, KIM S K, et al. Improved photovoltaic performance and stability of quantum dot sensitized solar cells using Mn-ZnSe shell structure with enhanced light absorption and recombination control[J]. Nanoscale, 2015, 7(29):12552-12563. DOI:10.1039/c5nr03291a.
[22] MENG K, SUROLIA P K, BYRNE O, et al. Efficient CdS quantum dot sensitized solar cells made using novel Cu₂S counter electrode[J]. Journal of Power Sources, 2014, 248:218-223. DOI:10.1016/j.jphotochem.2019.03.044.
[23] KHODAM F, AMANI-GHADIM A R, ABER S. Preparation of CdS quantum dot sensitized solar cell based on ZnTi-layered double hydroxide photoanode to enhance photovoltaic properties[J]. Solar Energy, 2019, 181:325-332. DOI:10.1016/j.solener.2019.02.019.
[24] LIU D, LIU J, LIU J, et al. The photovoltaic performance of CdS/CdSe quantum dots co-sensitized solar cells based on zinc titanium mixed metal oxides[J]. Physica E: Low-dimensional Systems and Nanostructures, 2020, 115:113669. DOI:10.1016/j.physe.2019.113669.
[25] LV K, SHI C, MA C, et al. Introduction of polysulfide anions to increase the loading quantity of PbS quantum-dots for efficient solid-state quantum-dot sensitized TiO₂ nanorod array solar cells[J]. Journal of Nanoparticle Research, 2019, 21(1):2. DOI:10.1007/s11051-018-4446-5.
[26] ESPARZA D, ZARAZU 'A I, LÓPEZ-LUKE T, et al. Photovoltaic properties of Bi₂S₃ and CdS quantum dot sensitized TiO₂ solar cells[J]. Electrochimica Acta, 2015, 180:486-492. DOI:10.1016/j.electacta.2015.08.102.
[27] LI W, PENG Z, SUN Z, et al. Orientation modulation of ZnO nanorods on charge transfer performance enhancement for Sb₂S₃ quantum dot sensitized solar cells[J]. Journal of Alloys and Compounds, 2020, 816:152628. DOI:10.1016/j.jallcom.2019.152628.
[28] ZHANG Q, GUO X, HUANG X, et al. Highly efficient CdS/CdSe-sensitized solar cells controlled by the structural properties of compact porous TiO₂ photoelectrodes[J]. Physical Chemistry Chemical Physics, 2011, 13(10):4659-4667. DOI:10.1039/c0cp02099k.
[29] BRAGA A, GIMÉNEZ S, CONCINA I, et al. Panchromatic sensitized solar cells based on metal sulfide quantum dots grown directly on nanostructured TiO₂ electrodes[J]. The Journal of Physical Chemistry Letters, 2011, 2(5):454-460. DOI:10.1021/jz2000112.
[30] GONZÁLEZ-PEDRO V, SIMA C, MARZARI G, et al. High performance PbS quantum dot sensitized solar cells exceeding 4% efficiency: the role of metal precursors in the electron injection and charge separation[J]. Physical Chemistry Chemical Physics, 2013, 15(33):13835-13843. DOI:10.1039/c3cp51651b.
[31] DU J, DU Z, HU J S, et al. Zn-Cu-In-Se quantum dot solar cells with a certified power conversion efficiency of 11.6%[J]. Journal of the American Chemical Society, 2016, 138(12):4201-4209. DOI:10.1021/jacs.6b00615.
[32] YANG J, ZHONG X. CdTe based quantum dot sensitized solar cells with efficiency exceeding 7% fabricated from quantum dots prepared in aqueous media[J]. Journal of Materials Chemistry A, 2016, 4(42):16553-16561. DOI:10.1039/c6ta07399a.
[33] LI L, YANG X, ZHANG W, et al. Boron and sulfur co-doped TiO₂ nanofilm as effective photoanode for high efficiency CdS quantum-dot-sensitized solar cells[J]. Journal of Power Sources, 2014, 272:508-512. DOI:10.1016/j.jpowsour.2014.08.116.
[34] BAI Y, HAN C, CHEN X, et al. Boosting the efficiency of quantum dot sensitized solar cells up to 7.11% through simultaneous engineering of photocathode and photoanode[J]. Nano Energy, 2015, 13:609-619. DOI:10.1016/j.nanoen.2015.04.002.
[35] ZARBSKA K, ŁCKI T, SKOMPSKA M. Synthesis of CdSe on FTO-supported ZnO nanorods by SILAR and electrochemical methods and comparison of photoelectrochemical properties of FTO/ZnO/CdSe systems in aqueous S^2-/S^2-_n electrolyte[J]. Journal of Electroanalytical Chemistry, 2018, 819:459-468. DOI:10.1016/j.jelechem.2017.12.036.
[36] LEE J W, SON D Y, AHN T K, et al. Quantum-dot-sensitized solar cell with unprecedentedly high photocurrent[J]. Scientific Reports, 2013, 3:1050. DOI:10.1038/srep01050.
[37] BHANDE S S, AMBADE R B, SHINDE D V, et al. Improved photoelectrochemical cell performance of Tin oxide with functionalized multiwalled carbon nanotubes-cadmium selenide sensitizer[J]. ACS Applied Materials & Interfaces, 2015, 7(45):25094-25104. DOI:10.1021/acsami.5b05385.
[38] KUMAR D K, LOSKOT J, K(ˇoverR)Í(ˇoverZ)J, et al. Synthesis of SnSe quantum dots by successive ionic layer adsorption and reaction(SILAR)method for efficient solar cells applications[J]. Solar Energy, 2020, 199:570-574. DOI:10.1016/j.solener.2020.02.050.
[39] 舒婷. 量子点敏化太阳能电池电解质的研究进展[J]. 化学工程师, 2013,27(4): 42-44. DOI:10.3969/j.issn.1002-1124.2013.04-013.
[40] DENG Y, LU S, XU Z, et al. Enhanced performance of CdS/CdSe quantum dot-sensitized solar cells by long-persistence phosphors structural layer[J]. Science China Materials, 2020, 63(4):516-523. DOI:10.1007/s40843-019-1248-6.
[41] LEE H J, CHANG D W, PARK S M, et al. CdSe quantum dot(QD)and molecular dye hybrid sensitizers for TiO₂ mesoporous solar cells: working together with a common hole carrier of cobalt complexes[J]. Chemical Communications, 2010, 46(46): 8788-8790. DOI:10.1039/c0cc03808c.
[42] CHEBROLU V T, KIM H J. Recent progress in quantum dot sensitized solar cells: an inclusive review of photoanode, sensitizer, electrolyte, and the counter electrode[J]. Journal of Materials Chemistry C, 2019, 7(17):4911-4933. DOI:10.1039/c8tc06476h.
[43] ZHAO K, YU H, ZHANG H, et al. Electroplating cuprous sulfide counter electrode for high-efficiency long-term stability quantum dot sensitized solar cells[J]. The Journal of Physical Chemistry C, 2014, 118(11):5683-5690. DOI:10.1021/jp4118369.
[44] TYAGI J, GUPTA H, PUROHIT L P. Cascade structured ZnO/TiO₂/CdS quantum dot sensitized solar cell[J]. Solid State Sciences, 2020, 102:106176. DOI:10.1016/j.solidstatesciences.2020.106176.
[45] GUO W, ZHANG X, YU R, et al. CoS NWs/Au hybridized networks as efficient counter electrodes for flexible sensitized solar cells[J]. Advanced Energy Materials, 2015, 5(11):1500141. DOI:10.1002/aenm.201500141.
[46] WANG G, DONG W, MA P, et al. Interconnected nitrogen and sulfur co-doped graphene-like porous carbon nanosheets with high electrocatalytic activity as counter electrodes for dye-sensitized and quantum dot-sensitized solar cells[J].Electrochimica Acta, 2018, 290: 273-281. DOI: 10.1016/j.electacta. 2018.09.063.
[47] HESSEIN A, EL-MONEIM A A. Hybrid CuS-PEOT: PSS counter electrode for quantum sensitized solar cell[J].Optik, 2019, 193: 162974. DOI: 10.1016/j.ijleo.2019.162974.
[48] CHEN Y, ZHANG X, TAO Q, 2015. High catalytic activity of a PbS counter electrode prepared via chemical bath deposition for quantum dots-sensitized solar cells[J]. RSC Advances, 2015, 5(3), 1835-1840. DOI: 10.1039/c4ra08076a.
[49] QUY V H V, VIJAYAKUMAR E, HO P, et al. Electrodeposited MoS₂ as electrocatalytic counter electrode for quantum dot-and dye-sensitized solar cells[J]. Electrochimica Acta, 2018, 260: 716-725. DOI. 10.1016/j.electacta.2017.12.023.
[50] SARKAR A, BERA S, CHAKROBORTY A. NiS/rGO nanohybrid: an excellent counter electrode for dye sensitized solar cell[J].Solar Energy Materials and Solar Cells,2018,182: 314-320. DOI.10.1016/j.solmat.2018.03.026.
[51] GOPI C V, BAE J H, VENKATA-HARITHA M, et al. One-step synthesis of solution processed time-dependent highly efficient and stable PbS counter electrodes for quantum dot-sensitized solar cells[J]. RSC Advances, 2015, 130:107522-107532. DOI:10.1039/c5ra22715a.
[52] SELOPAL G S, CONCINA I, MILAN R, et al. Hierarchical self-assembled Cu₂S nanostructures: Fast and reproducible spray deposition of effective counter electrodes for high efficiency quantum dot solar cells[J]. Nano Energy, 2014, 6:200-210. DOI:10.1016/j.nanoen.2014.04.003.
[53] LUO S, KE J, YUAN M, et al. CuInS₂ quantum dots embedded in Bi₂WO₆ nanoflowers for enhanced visible light photocatalytic removal of contaminants[J]. Applied Catalysis B: Environmental, 2018, 221:215-222. DOI:10.1016/j.apcatb.2017.09.028.

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