NiO光电阴极膜厚对量子点敏化太阳能电池性能的影响

王森阳; 张兆有; 孙杰; 梁城洋; 曹颖; 耿仕通; 李玲

doi:10.3969/j.issn.1000-1565.2023.05.007

河北大学学报(自然科学版) >

2023 , Vol. 43 >Issue 5: 492 - 499

DOI: https://doi.org/10.3969/j.issn.1000-1565.2023.05.007

NiO光电阴极膜厚对量子点敏化太阳能电池性能的影响

王森阳 ,
张兆有 ,
孙杰 ,
梁城洋 ,
曹颖 ,
耿仕通 ,
李玲

展开

王森阳(1999—),女,河南南阳人,河北大学在读硕士研究生,主要从事量子点纳米材料及光电器件研究.
E-mail:way451817@163.com

收稿日期: 2023-02-18

网络出版日期: 2023-10-25

基金资助

国家自然科学基金资助项目(52271209);河北省自然科学基金重点资助项目(E2020201030);京津冀协同创新共同体建设专项(21344301D);河北大学2022年大学生创新创业计划训练资助项目(2022169;2022165;2022170)

收起

Effect of NiO photocathode film thickness on the performance of quantum dot sensitized solar cells

WANG Senyang ,
ZHANG Zhaoyou ,
SUN Jie ,
LIANG Chengyang ,
CAO Ying ,
GENG Shitong ,
LI Ling

Expand

Hebei Key Lab of Optic-electronic Information and Materials, Hebei Provincial Photovoltaic Technology Collaborative Innovation Center, College of Physics Science and Technology, Hebei University, Baoding 071002, China

Received date: 2023-02-18

Online published: 2023-10-25

Fold

摘要

为探究量子点敏化太阳能电池(QDSSCs)中光阳极薄膜材料的最佳制备条件,通过一步高温水热法合成p型NiO纳米颗粒,并采用超声法将其制备成NiO浆料,丝网印刷在导电玻璃上以形成NiO薄膜.NiO薄膜可作为量子点敏化太阳能电池的光电阴极,结合Cu₂S对电极和多硫化物电解质组装成太阳能电池.通过对不同膜厚NiO光电阴极薄膜的研究及反复测试,结果表明:当NiO薄膜材料膜厚为21 μm时该电池存在最高的光电转换效率.

关键词： 量子点敏化太阳能电池; NiO薄膜; 材料膜厚; 光电转化效率

本文引用格式

王森阳 , 张兆有 , 孙杰 , 梁城洋 , 曹颖 , 耿仕通 , 李玲 . NiO光电阴极膜厚对量子点敏化太阳能电池性能的影响[J]. 河北大学学报(自然科学版), 2023 , 43(5) : 492 -499 . DOI: 10.3969/j.issn.1000-1565.2023.05.007

Abstract

This work is to explore the best preparation conditions of photoanode film materials in quantum dot sensitized solar cells(QDSSCs). P-type NiO nanoparticles are synthetized by one-step high temperature hydrothermal method, which is then screen printed on conductive glass to form NiO films. NiO films can be used as photocathode for quantum dot sensitized solar cells. Combine with Cu₂S counter electrode, solar cells are assembled. NiO photocathode films with different film thicknesses were studied and tested repeatedly. The results show that the highest photoelectric conversion efficiency is achieved when the film thickness of NiO film material is 21 μm.

Key words： quantum dot-sensitized solar cell; NiO film; material film thickness; electrochemical performance

参考文献

[1] JUN H K, TUNG H T. A short overview on recent progress in semiconductor quantum dot-sensitized solar cells[J]. J Nanomater, 2022, 2022: 1-7. DOI: 10.1155/2022/1382580.
[2] SAHU A, GARG A, DIXIT A. A review on quantum dot sensitized solar cells: past, present and future towards carrier multiplication with a possibility for higher efficiency[J]. Sol Energy, 2020, 203: 210-239. DOI: 10.1016/j.solener.2020.04.044.
[3] RASAL A S, YADAV S, KASHALE A A, et al. Stability of quantum dot-sensitized solar cells: a review and prospects[J]. Nano Energy, 2022, 94: 106854. DOI: 10.1016/j.nanoen.2021.106854.
[4] SHEN K, LUO G, LIU J, et al. Highly transparent photoelectrochromic device based on carbon quantum dots sensitized photoanode[J]. Sol Energy Mat Sol C, 2019, 193: 372-378. DOI: 10.1016/j.solmat.2019.01.004.
[5] GANGADHAR L, PRASEETHA P K. A novel modeling of quantum dot sensitized solar cells[J]. J Comput Theor Nanosci, 2019, 16(2): 389-392. DOI: 10.1166/jctn.2019.7737.
[6] DU Z L, ARTEMYEV M, WANG J, et al. Performance improvement strategies for quantum dot-sensitized solar cells: a review[J]. J Mater Chem A, 2019, 7(6): 2464-2489. DOI: 10.1039/C8TA11483H.
[7] SINGH S, KHAN Z H, KHAN M B, et al. Quantum dots-sensitized solar cells: a review on strategic developments[J].B Mater Sci, 2022, 45(2): 1-13. DOI: 10.1007/s12034-022-02662-z.
[8] LI Z, YU L B, WANG H, et al. TiO₂ passivation layer on ZnO hollow microspheres for quantum dots sensitized solar cells with improved light harvesting and electron collection[J]. Nanomaterials, 2020, 10(4): 631. DOI: 10.3390/nano10040631.
[9] HE J J, LINDSTR M H, HAGFELDT A, et al. Dye-sensitized nanostructured p-type nickel oxide film as a photocathode for a solar cell[J]. J Phys Chem B, 1999, 103(42): 8940-8943. DOI: 10.1021/jp991681r.
[10] ALVARADO-ARAMBURO A, GONZALEZ-ORTIZ L J, GARCIA-BON M A, et al. The recent use of nanoporous materials in the development of third-generation solar cells: a review[J]. IEEE Nanotechnol Mag, 2021, 15(2): 37-48. DOI: 10.1109/MNANO.2020.3048092.
[11] BONOMO M, EKOI E J, MARRANI A G, et al. NiO/ZrO₂ nanocomposites as photocathodes of tandem DSCs with higher photoconversion efficiency with respect to parent single-photoelectrode p-DSCs[J]. Sustain Energy Fuels, 2021, 5(18): 4736-4748. DOI: 10.1039/D1SE00566A.
[12] PAN Z X, YUE L, RAO H S, et al. Boosting the performance of environmentally friendly quantum dot-sensitized solar cells over 13% efficiency by dual sensitizers with cascade energy structure[J]. Adv Mater, 2019, 31(49): 1903696. DOI: 10.1002/adma.201903696.
[13] POTTS N T Z, SLOBODA T, W CHTLER M, et al. Probing the dye-semiconductor interface in dye-sensitized NiO solar cells[J]. J Chem Phys, 2020, 153(18): 184704. DOI: 10.1063/5.0023000.
[14] GELETA T A, IMAE T. Nanocomposite photoanodes consisting of p-NiO/n-ZnO heterojunction and carbon quantum dot additive for dye-sensitized solar cells[J]. ACS Appl Nano Mater, 2021, 4(1): 236-249. DOI: 10.1021/acsanm.0c02547.
[15] SULTAN U, AHMADLOO F, CHA G, et al. A high-field anodic NiO nanosponge with tunable thickness for application in p-type dye-sensitized solar cells[J]. ACS Appl Energy Mater, 2020, 3(8): 7865-7872. DOI: 10.1021/acsaem.0c01249.
[16] QU J, ZHANG K, GAMAL H, et al. Triple-shell NiO hollow sphere for p-type dye-sensitized solar cell with superior light harvesting[J]. Sol Energy, 2021, 216: 238-244. DOI: 10.1016/j.solener.2021.01.026.
[17] NATTESTAD A, MOZER A J, FISCHER M K R, et al. Highly efficient photocathodes for dye-sensitized tandem solar cells[J]. Nat Mater, 2010, 9(1): 31-35. DOI: 10.1038/nmat2588.
[18] TIAN H N, XU B, CHEN H, et al. Solid-state perovskite-sensitized p-type mesoporous nickel oxide solar cells[J]. Chem Sus Chem, 2014, 7(8): 2150-2153. DOI: 10.1002/cssc.201402032.
[19] BENAZZI E, MALLOWS J, SUMMERS G H, et al. Developing photocathode materials for p-type dye-sensitized solar cells[J]. J Mater Chem C, 2019, 7(34): 10409-10445. DOI: 10.1039/C9TC01822K.
[20] BONOMO M, DI GIROLAMO D, PICCINNI M, et al. Electrochemically deposited NiO films as a blocking layer in p-type dye-sensitized solar cells with an impressive 45% fill factor[J]. Nanomaterials, 2020, 10(1): 167. DOI: 10.3390/nano10010167.
[21] XU B, TIAN L, ETMAN A S, et al. Solution-processed nanoporous NiO-dye-ZnO photocathodes: toward efficient and stable solid-state p-type dye-sensitized solar cells and dye-sensitized photoelectrosynthesis cells[J]. Nano Energy, 2019, 55: 59-64. DOI: 10.1016/j.nanoen.2018.10.054.
[22] DAENEKE T, YU Z, LEE G P, et al. Dominating energy losses in NiO p-type dye-sensitized solar cells[J]. Adv Energy Mater, 2015, 5(4): 1401387. DOI: 10.1002/aenm.201401387.
[23] MACDONALD T J, MANGE Y J, DEWI M R, et al. CuInS₂/ZnS nanocrystals as sensitisers for NiO photocathodes[J]. J Mater Chem A, 2015, 3(25): 13324-13331. DOI: 10.1039/C5TA01821H.
[24] RAISSI M, PELLEGRIN Y, JOBIC S, et al. Infra-red photoresponse of mesoscopic NiO-based solar cells sensitized with PbS quantum dot[J]. Sci Rep, 2016, 6: 24908. DOI: 10.1038/srep24908.
[25] LIU S, LIU L, DU Q Z, et al. Preparation of PbS/NiO composite photocathode and their applications in quantum dot sensitized solar cells[J]. J New Mater Electr Sys, 2020, 23(1): 7-12. DOI: 10.14447/jnmes.v23i1.a02. (

Options

文章导航

模态框（Modal）标题

摘要

本文引用格式

Abstract

参考文献