Synthesis of naphthyl-perimidium based receptor and selective recognition of fluoride

doi:10.3969/j.issn.1000-1565.2020.04.006

Abstract

Abstract: A novel naphthyl-perimidium based receptor 1 was synthesized. The interaction between receptor 1 and nine common anions(F^-, Cl^-, Br^-, I^-, CH₃COO^-, HSO^-₄, H₂PO₄^-, ClO₄^-, NO^-₃)were studied by UV-Vis and FL spectroscopies. The results indicated that receptor 1 should selective recognition of F^-. In UV-Vis spectra, When F^- was added, the color of receptor 1 solution changed from yellow to colorless, the results indicated that 1 could behave as a colorimetric chemosensor for F^-. Job plot demonstrated that receptor 1 formed 1∶1 complex with F^-, and the binding constant is(3.05±0.15)×10³ L/mol. In fluorescent spectra, the non-fluorescent solution of 1 exhibited strong blue fluorescence when F^- was added, and a strong emission peak at 403 nm was found with the turn-on effect. The detection linear range for F^- was 1.0×10^-6—3.0×10^-5 mol/L, and the detection limit was 8.5×10^-6 mol/L. The ¹H NMR investigation confirmed that the hydrogen bond was formed between F^- and the C(2)-H of receptor 1, the excessive of F^- will cause deprotonation of receptor 1.

Key words: perimidium, fluoride, colorimetric recognition, fluorescent probe

CLC Number:

DONG Zhiyun, JIA Jia, WANG Shimei, XI Fugui. Synthesis of naphthyl-perimidium based receptor and selective recognition of fluoride[J]. Journal of Hebei University (Natural Science Edition), 2020, 40(4): 372-378.

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