Journal of Hebei University(Natural Science Edition) >

2010 , Vol. 30 >Issue 1: 43 - 48

DOI: https://doi.org/10.3969/j.issn.1000-1565.2010.01.010

Kinetics and Mechanism of Oxidation of 1,3-Propanediamine by Diperiodatocuprate(Ⅲ) in Alkaline Medium

  • SHAN Jin-huan ,
  • WANG Xiao-qian ,
  • HAN Chong ,
  • WANG Fang
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Online published: 2010-01-25

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Abstract

In order to provide a strong basis for the path of organic synthesis, the kinetics of oxidation of 1,3-propanediamine (PDA) by diperiodatocuprater(Ⅲ) (DPC) in alkaline medium have been studied by spectrophotometry in a temperature range of 298.2～313.2 K. The reaction showed pseudo-first order with respect to DPC and 1

Key words： diperiodatocuprate(Ⅲ); 1,3-propanediamine; redox reaction

Cite this article

SHAN Jin-huan , WANG Xiao-qian , HAN Chong , WANG Fang . Kinetics and Mechanism of Oxidation of 1,3-Propanediamine by Diperiodatocuprate(Ⅲ) in Alkaline Medium[J]. Journal of Hebei University(Natural Science Edition), 2010 , 30(1) : 43 -48 . DOI: 10.3969/j.issn.1000-1565.2010.01.010

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