Journal of Hebei University (Natural Science Edition) ›› 2010, Vol. 30 ›› Issue (1): 43-48.DOI: 10.3969/j.issn.1000-1565.2010.01.010

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Kinetics and Mechanism of Oxidation of 1,3-Propanediamine by Diperiodatocuprate(Ⅲ) in Alkaline Medium

SHAN Jin-huan,WANG Xiao-qian,HAN Chong,WANG Fang   

  • Online:2010-01-25 Published:2010-01-25

Abstract: In order to provide a strong basis for the path of organic synthesis, the kinetics of oxidation of 1,3-propanediamine (PDA) by diperiodatocuprater(Ⅲ) (DPC) in alkaline medium have been studied by spectrophotometry in a temperature range of 298.2~313.2 K. The reaction showed pseudo-first order with respect to DPC and 1

Key words: diperiodatocuprate(Ⅲ), 1,3-propanediamine, redox reaction

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