基于Ni2+氧化性和磷酸酯缓蚀性制备水性铝颜料

doi:10.3969/j.issn.1000-1565.2015.01.007

河北大学学报(自然科学版) ›› 2015, Vol. 35 ›› Issue (1): 34-39.DOI: 10.3969/j.issn.1000-1565.2015.01.007

基于Ni2+氧化性和磷酸酯缓蚀性制备水性铝颜料

马志领，李翠翠，位会棉

河北大学化学与环境科学学院，保定 071002

收稿日期:2014-10-15 发布日期:2015-01-25
通讯作者: 马志岭
作者简介:马志领（1964-），女，回族，河北河间人，河北大学教授，博士，主要从事阻燃材料及铝颜料的研究
基金资助:
河北省教育厅科学研究计划项目（E2014201076）

The properation of waterbone aluminum pigment based on oxidizing of Ni2+ and corrosion inhibition of phosphate

MA Zhiling, LI Cuicui, WEI Huimian

College of Chemistry and Environmental Science, Hebei University,Baoding 071002, China

Received:2014-10-15 Published:2015-01-25
Contact: MA Zhiling

摘要/Abstract

摘要： 本文借助于Ni2+氧化金属铝实现铝颜料表面的羟基化，以酚醚型磷酸酯(TXP-10)作为缓蚀剂制备了缓蚀型水性铝颜料.红外光谱(FTIR)和X射线衍射(XRD)测定表明，镍离子氧化金属铝在铝颜料表面形成勃母石结构的氧化铝的水合物，勃母石可吸附TXP-10达到缓蚀目的.探讨了反应介质组成及pH值、NiSO4?7H2O和TXP-10的用量等对缓蚀性能的影响.结果表明：40.00 g铝粉在中性的异丙醇/水的体积比为100/15的反应介质中，0.30 g NiSO4?7H2O羟基化作用下，吸附4.00 g TXP-10，可制得缓蚀性能最佳的水性铝颜料.

关键词: 水性铝颜料, 铝粉表面羟基化, 酚醚型磷酸酯, 吸附, 缓蚀性

Abstract: The corrosion inhibition waterborne aluminum pigments were prepared by using NiSO4?7H2O oxidized aluminum to make the surface hydroxylation, and the phenol ether phosphate TXP-10 as the corrosion inhibitor. FTIR and XRD results indicated that nickel ion oxidized aluminum on the aluminum pigment surface formed the boehmite structure aluminum oxyhydroxide, and the boehmite can adsorbe TXP-10 to achieve the corrosion inhibition. The influence on corrosion inhibition by composition and pH value of the preparation medium, the dosage of NiSO4?7H2O and TXP - 10 were studied. The results showed that at neutral condition, 40.00 g aluminum pigment was oxidized by 0.30 g NiSO4?7H2O in the volume ratio of isopropyl alcohol/water = 100/15, and 4.00 g TXP-10 were adsorped, the waterborne aluminum pigments exhibited best corrosion resistance.

Key words: waterborne aluminum pigments, surface hydroxylated aluminum pigments, phenol ether phosphate, adsorption, corrosion inhibition

中图分类号:

TG174

马志领，李翠翠，位会棉. 基于Ni2+氧化性和磷酸酯缓蚀性制备水性铝颜料[J]. 河北大学学报(自然科学版), 2015, 35(1): 34-39.

MA Zhiling, LI Cuicui, WEI Huimian. The properation of waterbone aluminum pigment based on oxidizing of Ni2+ and corrosion inhibition of phosphate[J]. Journal of Hebei University (Natural Science Edition), 2015, 35(1): 34-39.

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基于Ni2+氧化性和磷酸酯缓蚀性制备水性铝颜料

The properation of waterbone aluminum pigment based on oxidizing of Ni2+ and corrosion inhibition of phosphate

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