稀土离子La3+修饰纳米TiO2-xFx光催化性能研究

doi:10.3969/j.issn.1000-1565.2015.02.003

河北大学学报(自然科学版) ›› 2015, Vol. 35 ›› Issue (2): 122-127.DOI: 10.3969/j.issn.1000-1565.2015.02.003

稀土离子La3+修饰纳米TiO2-xFx光催化性能研究

马晓燕，张荣香，李玲，赵晓辉

河北省光电信息材料重点实验室，河北大学物理科学与技术学院，河北保定，071002

收稿日期:2014-10-10 修回日期:2014-12-12 出版日期:2015-03-25 发布日期:2015-03-25
通讯作者: 赵晓辉
作者简介:马晓燕（1980-），女，宁夏银川人，河北大学助理实验师
基金资助:
国家自然科学基金项目（21201053）、河北省教育厅重点基金项目（ZD 20131089）

Photocatalytic properties of rare earth La3+ ion modified Nano-TiO2-xFx

MA Xiaoyan, ZHANG Rongxiang, LI Ling，ZHAO Xiaohui

Key Laboratory of Hebei Optic-electronic Information Material, College of Physics Science and Technology, HebeiUniversity, Baoding 071002, China

Received:2014-10-10 Revised:2014-12-12 Online:2015-03-25 Published:2015-03-25
Contact: ZHAO Xiaohui

摘要/Abstract

摘要： 以四氯化钛、硝酸镧、硫脲、氟化铵、氨水等为主要实验药品，采用常温络合-控制水解法制备具有可见光催化活性的La离子修饰纳米TiO2-xFx光触媒乳液.使用XRD、UV-Vis、纳米激光粒度分析仪等表征了样品的物相、粒径、组成、光吸收等性质.在光照下，考察了La修饰纳米TiO2-xFx光触媒乳液降解酸性红3R的光催化性能.结果表明，当La掺杂浓度为0.1%，F掺杂浓度为0.3%，体系pH值为6，回流时间为15min，样品乳液对酸性红3R染料的降解率达到95%以上.

关键词: La修饰, 纳米TiO2-xFx, 常温络合-控制水解, 光催化

Abstract: The La ion-modified nanometer TiO2-xFx photocatalyst emulsion with visible light photocatalytic activity was synthesized by using complexation-controlled hydrolysis at room temperature with titanium tetrachloride, lanthanum nitrate, thiourea, ammonium fluoride, ammonia as raw materials. The sample phase, particle size, composition, and light absorption properties were characterized by using XRD, UV-Vis, and Nanometer laser particle size analyzers. Under the sunlight, the photocatalytic performance of La-modified TiO2-xFx emulsion through degradating acid red 3R dye was investigated. The results show that when the La doping concerntration is 0.1%, F doping concerntration is 0.3%, the pH value is 6, and reflux time is 15 min, the degradation of acid red 3R dye is more than 95%.

Key words: La modified, nanometer-TiO2-xFx, complexation-controlled hydrolysis at room temperature, photocatalytic

中图分类号:

TQ613.1

马晓燕，张荣香，李玲，赵晓辉. 稀土离子La3+修饰纳米TiO2-xFx光催化性能研究[J]. 河北大学学报(自然科学版), 2015, 35(2): 122-127.

MA Xiaoyan, ZHANG Rongxiang, LI Ling，ZHAO Xiaohui. Photocatalytic properties of rare earth La3+ ion modified Nano-TiO2-xFx[J]. Journal of Hebei University (Natural Science Edition), 2015, 35(2): 122-127.

参考文献

[1] FUJISHIMA A, HONDA K. TiO2 photoelectrochemistry and photocatalysis[J]. Nature, 1972, 238, 37-38.
[2] LEGRINI O, OILVEROS E, BRAUN A M. Photochemical Processes for Water Treatment[J]. Chem Rev 1993, 93, 671-698.
[3] LIANG Chunhua, LI Fangbai, LIU Chengshuai, et al. The enhancement of absorption and photocatalytic activity of rare earth ions doped TiO2 for the degradation of Orange I[J]. Dyes and Pigments, 2008, 76(2), 477-484.
[4] BINGHAM S, DAOUD W A. Recent advances in making nano-sized TiO2 visible-light active through rare-earth metal doping[J]. J Mater Chem, 2011, 21, 2041-2050.
[5] LI Jinhuan, YANG Xia, YU Xiaodan, et al. Rare earth oxide-doped titania nanocomposites with enhanced phocatalytic activity towards the degradation of partially hydrolysis polyacrylamide[J]. Applied Surface Science, 2009, 255(6): 3731-3738.
[6] SHI Zhongjiang, ZHANG Xiaoyan, YAO Shuhua. Synthesis and photocatalytic properties of lanthaum doped anatase TiO2 coated Fe3O4 composites[J]. Rare Metals, 2011, 30(3): 25-257.
[7] JIN Minji, NAGAOKA Y, NISHI K, et al. Adsorption properties and photocatalytic activity of TiO2 and La-doped TiO2. Adsorption, 2008, 14: 257-263.
[8] DAI Ke, PENG Tianyou, CHEN Hao, et al. Photocatalytic Degradation of Commercial Phoxin over La-Doped TiO2 Nanoparticles in Aqueous Suspension[J]. Environ Sci Technol., 2009, 43(5): 1540-1545.
[9] ASAHI R, MORIKAWA T, OHWAKI T, et al. Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides[J]. Science, 2001, 293, 269-271.
[10] YUAN Jvjun, LI Hongdong, GAO Shiyong, et al. A facile route to n-type TiO2-nanotube/P-type boron-doped- diamond heterojunction for higlly efficient photocatalysts[J]. Chem Commun, 2010, 46, 3119-3121.
[11] WANG Xingdong, BLACKFORD M, PRINCE K, et al. Preparation of Boron-Doped Porous Titania Networks Containing Gold Nanoparticles with Enhanced Visible-Light Photocatalytic Activity[J]. ACS Appl Mater Interfaces 2012, 4: 476-482.
[12] NAM Sanghun Nam, KIM T K, BOO J H. Physical property and photo-catalytic activity of sulfur doped TiO2 catalysts responding to visible light[J]. Catalysis Today, 185(1): 259-262.
[13] CHAUDHURI R G, PARIA S. Visible light induced photocatalytic activity of sulfur doped hollow TiO2 nanoparticles synthesized via a novel route[J]. Dalton Trans, 2014, 43, 5526-5534.
[14] DUNNILL C W, PARKIN I P. Nitrogen-doped TiO2 thin films: photocatalytic applications for healthcare environments[J]. Dalton Trans, 2011, 40, 1635-1640.
[15] VARLEY J B, JANOTTI A, VANDEWALLE C G. Mechanism of Visible-Light Photocatalysis in Nitrogen-Doped TiO2[J]. Advanced Materials, 2011, 23(20): 2343-2347.
[16] DOZZI M V, D’ANDREA C, OHTANI B, et al. Fluorine-Doped TiO2 Materials: Photocatalytic Activity vs Time- Resolved Photoluminescence[J]. J Phys Chem C, 2013, 117(48): 25586-25595.
[17] LV K, CHENG Bei, YU Jiaguo, et al. Fluorine ions-mediated morphology control of anatase TiO2 with enhanced photocatalytic activity[J]. Phys Chem Chem Phys, 2012, 14, 5349-5362.
[18] YU Ying, WU Haihong, ZHU Baolin, et al. Preparation, Characterization and Photocatalytic Activities of F-doped TiO2 Nanotubes[J]. Catalysis Letters, 2008, 121(1-2): 165-171.
[19] WU Guosheng, WANG Jinpeng, THOMAS D F, et al. Synthesis of F-Doped Flower-like TiO2 Nanstructures with High Photoelectrochemical Activity[J]. Langmuir, 2008, 24(7): 3503-3509.
[20] ZHOU Jinkai, LV Lu, YU Jianqiang, et al. Synthesis of Self-Organized Polycrystalline F-doped TiO2 Hollow Microspheres and Their Photocatalytic Activity under Visible Light[J]. J Phys Chem C, 2008, 112(14): 5316-5321.
[21] 张学军,马旭红,林立,等.Ce/S共掺杂TiO2制备及其光催化活性[J]. 湖南城市学院学报(自然科学版), 2013, 22(1): 67-69.
ZHANG Xuejun, MA Xuhong, LIN Li, et al. Prparation and Photocatalytic Activity of Cerium and Sulfur Co-doped Titanium Dioxide[J]. Journal of Hunan City Unversity (Natural Science), 2013, 22(1): 67-69.
[22] CONG Ye, ZHANG Jinlong, CHEN Feng, et al. Preparation, Photocatalytic Activity, and Mechanism of Nano-TiO2 Co-Doped with Nitrogen and Iron(III)[J]. J Phys Chem C, 2007, 111, 10618-10623.

稀土离子La3+修饰纳米TiO2-xFx光催化性能研究

Photocatalytic properties of rare earth La3+ ion modified Nano-TiO2-xFx

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	雷源,刘桂随,朱爱雪,李牧原,刘芃岩. 可见光催化降解水中邻苯二甲酸二丁酯[J]. 河北大学学报(自然科学版), 2022, 42(5): 474-482.
[2]	刘雪梅,郭珂欣,李金环,李慧敏,胡若晖. 季铵盐阳离子的Waugh型化合物的合成与表征[J]. 河北大学学报(自然科学版), 2022, 42(3): 265-272.
[3]	刘双安,单一洋,唐浩然,李孟,陈嘉信,袁小先. 静电纺丝制备铕掺杂二氧化钛纳米纤维及其光催化性能[J]. 河北大学学报(自然科学版), 2020, 40(3): 255-259.
[4]	陶畅, 马志领, 刘渊博, 张春燕, 解飞. 多功能水性铝粉颜料的制备及应用[J]. 河北大学学报(自然科学版), 2019, 39(2): 159-165.
[5]	李梦悦,房国丽,张刚,魏杰,郑功. TiO₂/AC复合材料的吸附性与光催化性能[J]. 河北大学学报(自然科学版), 2018, 38(5): 480-489.
[6]	李晓苇,赵开封,胡晓雪,卢琪,眭慧东,李建伟,刘爽. 复合纳米TiO₂透明光触媒乳液的制备及性能[J]. 河北大学学报(自然科学版), 2017, 37(5): 464-470.
[7]	肖俊莹,许军,武承杰,眭慧东,丁文革. 铬掺杂纳米二氧化钛乳液的制备及其光催化性能[J]. 河北大学学报(自然科学版), 2016, 36(4): 353-357.
[8]	王明坤,太优一,崔彤,李晓苇,李玲. 硫掺杂纳米TiO₂透明溶胶的制备及性能[J]. 河北大学学报(自然科学版), 2016, 36(2): 124-128.
[9]	陈瑞雪,太优一,俞欢,郝文卓,李玲. 最小粒径钒/铁共掺杂纳米TiO2透明光触媒乳液的制备及其光催化性能[J]. 河北大学学报(自然科学版), 2015, 35(6): 582-588.
[10]	丁士文，柳涛，李桐，郭杨. 纳米二氧化钛-硅藻土复合材料的制备及性能[J]. 河北大学学报(自然科学版), 2015, 35(1): 27-33.
[11]	兰瑞家,李记太,周秋香,仇满德. TiO2/石墨烯复合材料的合成及其光催化性能[J]. 河北大学学报(自然科学版), 2013, 33(6): 608-613.
[12]	郭海军,仇满德,宋常英,翟永清,姚玉超. 不同的制备方法对纳米TiO2微结构及光催化性能的影响[J]. 河北大学学报(自然科学版), 2011, 31(4): 366-370.
[13]	丁士文,张红军,张永芬,张圆圆. 混晶纳米二氧化钛乳液光催化降解农药的研究[J]. 河北大学学报(自然科学版), 2010, 30(1): 49-52.
[14]	仇满德,姚子华,翟永清,张阿培,王旭,丁哲. 粉煤灰负载纳米TiO2的微区分析及应用[J]. 河北大学学报(自然科学版), 2008, 28(4): 384-389,402.
[15]	张永芬,赵菁,丁士文,王利勇. 混晶纳米TiO2分散乳液的制备及其光催化性能[J]. 河北大学学报(自然科学版), 2008, 28(4): 378-383.