Analysis of Baizi Yangxin pills and niuhuang jiedu pills by mid-infrared spectroscopy combined with chemometrics

doi:10.3969/j.issn.1000-1565.2018.03.006

Abstract

Abstract: The infrared spectrum has the advantages of high sensitivity,easy operation and strong specificity of bands.It is especially suitable for the rapid identification of Chinese herbal medicines.In this paper,ATR-MIR(attenuated total reflectance mid-infrared spectroscopy)was used to measure Baizi Yangxin pills and Niuhuang Jiedu pills,and then the two drugs were identified by chemometrics.The results show that the mid-infrared spectroscopy combined with chemometrics can achieve rapid detection and identification of Chinese herbal medicines.

Key words: infrared spectroscopy, Chinese herbal medicines, principal component analysis, derivative

CLC Number:

O657.3

LI Yankun,JIA Mingjing,WANG Han. Analysis of Baizi Yangxin pills and niuhuang jiedu pills by mid-infrared spectroscopy combined with chemometrics[J]. Journal of Hebei University (Natural Science Edition), 2018, 38(3): 262-267.

References

[1] 孙素琴,周群,秦竹,等.FT-IR和FT-Raman与中药的质量控制[J].光散射学报,2003,15(3): 203-207.DOI:10.3969/j.issn.1004-5929.2003.03.020. SUN S Q, ZHOU Q, QIN Z, et al. Quality control of traditional Chinese medicines by FT-IR and FT-raman[J].Chinese Journal of Light Scattering, 2003, 15(3): 203-207. DOI:10.3969/j.issn.1004-5929.2003.03.020.
[2] 谢晶曦,常俊标,王绪明.红外光谱在有机化学和药物化学中的应用[M].北京:科学出版社,2001.
[3] 刘军,红外光谱法在药物鉴别中的应用[J].天津药学,1995,7(2): 67-69.
[4] 李燕,吴然然,于佰华,等.红外光谱在中药定性定量分析中的应用[J].光谱学与光谱分析,2006,26(10): 1846-1849. LI Y, WU R R, YU B H, et al. A Review on applications of infrared spectroscopy to the study oftraditional Chinese medicine[J]. Spectroscopy and Spectral Analysis, 2006, 26(10): 1846-1849.
[5] 梅德强,王建华.红外光谱法研究中药进展[J].重庆大学学报(自然科学版),2003,26(11): 56-59. MEI D Q, WANG J H. The Development of research on Chinese drug by infrared spectroscopy[J].Journal of Chongqing University, 2003, 26(11): 56-59.
[6] 周殿凤.几种常见中药针剂的红外光谱分析[J].光散射学报,2009,21(1): 69-71. ZHOU D F. Infrared Spectroscopic analysis of some injections from Chinese traditional medicine[J]. Chinese Journal of Light Scattering, 2009, 21(1): 69-71.
[7] 陈晓霞,张宇.ATR红外光谱技术在药品包装材料检测中的应用[J].天津药学,2005,17(4): 20-22. CHEN X X, ZHANG Y. Application of ATR infrared spectrophotometry in analysis of drug packaging materials[J]. Tianjin Pharmacy, 2005, 17(4): 20-22.
[8] 顾小红,康继,汤坚.衰减全反射中红外光谱法用于葡萄酒的多酚检测[J].光谱学与光谱分析,2008,28(10): 33-34. GU X H, KANG J, TANG J. Quantification of polyphenols in wine by using ATR-MIR spectroscopy[J]. Spectroscopy and Spectral Analysis, 2008, 28(10): 33-34.
[9] HU J Q,MA X C,LIU L L.Rapid evaluation of the quality of chestnuts using near-infrared reflectance spectroscopy[J].Food Chemistry,2017,231: 141-147.DOI: 10.1016/j.foodchem.2017.03.127.
[10] 梁逸曾,俞汝勤.分析化学手册(第十分册-化学计量学)[M].北京:化学工业出社,2000.
[11] 梁逸曾.白灰黑复杂多组分分析体系及化学计量学算法[M].湖南科技出版社,1996.
[12] YADAV A K,CHANDLE S S.Identification of relevant input variables for prediction of 1-minute time step photovoltaic module power using Artificial Neural Network and Multiple Linear Regression Models[J].Renewable & Sustainable Energy Reviews,2017,77: 955-969.DOI: 10.1016/j.rser.2016.12.029.
[13] 韩晔华,霍飞凤,杨悠悠,等.中药指纹图谱研究的某些进展与展望[J].色谱,2008,26(2): 142. HAN Y H,HUO F F, YANG Y Y, et al. Some advances and prospects in finger printings of traditional Chinese medicines[J]. Chinese Journal of Chromatography, 2008, 26(2): 142.
[14] 周建良,齐炼文,李萍.色谱指纹图谱在中药质量控制中的应用[J].色谱,2008,26(2): 153. ZHOU J L, QI L W, LI P. Quality control of Chinese Herbal medicines with chromatographic fingerprints[J]. Chinese Journal of Chromatography, 2008, 26(2): 153.
[15] CANUTO B,TAILANDIA M,PEREIRA C F,et al.Red wines from South America: Content of phenolic compounds and chemometric distinction by origin[J].Microchemical Journal,2017,133: 114-120. DOI: 10.1016/j.microc.2017.03.018.
[16] TOMAS I,TORMOD N E S.The effect of multiplicative scatter correction(MSC)and linearity improvement in NIR spectroscopy[J].Applied Spectroscopy,1988,42(7): 1273-1284.
[17] ZHANG X,LU S H,LIAO Y,et al.Simultaneous determination of amino acid mixtures in cereal by using terahertz time domain spectroscopy and chemometrics[J].Chemometrics And Intelligent Laboratory Systems,2017,164: 8-15.DOI: 10.1016/j.chemolab.2017.03.001.
[18] BIN J,LI X,FAN W,et al.Calibration transfer of near-infrared spectroscopy by canonical correlation analysis coupled with wavelet transform[J].Analyst,2017,142(12): 2229-2238.DOI: 10.1039/c7an00280g.
[19] NOWAES C G,DA SILVA ROMAO L L,SANTOS B G,et al.Screening of Passiflora L.mineral content using principal component analysis and Kohonen self-organizing maps[J].Food Chemistry,2017,233: 507-513.DOI: 10.1016/j.foodchem.2017.04.111.
[20] WANG P,SUN H,LV H, et al.Thyroxine and reserpine-induced changes in metabolic profiles of rat urine and the therapeutic effect of Liu Wei Di Huang Wan detected by UPLC-HDMS[J].Journal of Pharmaceutical Biomedical Analysis,2010,53: 631-645.DOI: 10.1016/j.jpba.2010.04.032.
[21] YANG Z G,LI Q,LIU W Y,et al.Dual graph regularized NMF model for social event detection from Flickr data[J].World Wide Web-Internet and Web Information Systems,2017,20(5): 995-1015.DOI: 10.1007/s11280-016-0405-1.