Synthesis and thermometric performance of NaY9(SiO4)6O2:〓 Bi3+,Eu3+phosphor

doi:10.3969/j.issn.1000-1565.2022.06.005

Abstract

Abstract: To search probe phosphors with better performance temperature, using the ratio method of the fluorescence intensity, the thermosensitive performance of the NaY_9-x-y(SiO₄)₆O₂:xBi³⁺,yEu³⁺ phosphor has been studied. The results show the efficient energy transfer from Bi³⁺ to Eu³⁺ can be observed. With the excitation of Bi³⁺, the double emission spectra of Bi³⁺ and Eu³⁺ can be acquired. With the increase of the temperature, the fluorescence intensity quenching speed of Eu³⁺ is slower than that of Bi³⁺. Based on the temperature dependent fluorescence intensity ratio of Bi³⁺ to Eu³⁺, the relative sensitivity(S_r)values of the NaY_6.192(SiO₄)₆O₂:0.108Bi³⁺,2.7Eu³⁺ probe phosphor at the temperature range of 300 to 450 K have been calculated. The maximum(S_r)is 1.51 %·K^-1, which is much better than the suggested value of 0.3 %·K^-1 for the practical applications. The temperature probe phosphor in this work showed the potential in the temperature sensitivity fields.

Key words: phosphor, ratio method, thermosensitive performance, sensitivity

CLC Number:

FU Nian, YANG Zihan, MA Lianhua, WANG Chunhao, TU Yingying, LU Fachun. Synthesis and thermometric performance of NaY₉(SiO₄)₆O₂:〓 Bi³⁺,Eu³⁺phosphor[J]. Journal of Hebei University(Natural Science Edition), 2022, 42(6): 589-598.

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Synthesis and thermometric performance of NaY₉(SiO₄)₆O₂:〓 Bi³⁺,Eu³⁺phosphor

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