A new Waugh molybdate formulated as (NH4)2(C5H6N)4MnMo9O32·8H2O has been isolated by reacting of (NH4)6MnMo9O32·6H2O and pyridine in aqueous solution, and characterized by single X-ray diffraction, elemental analysis, IR and solid UV-Vis diffuse reflectance spectroscopy. Crystal structural analysis indicate that the title compound crystallizes in the monoclinic system with space group P21/c, a = 2.1805(17) nm, b = 1.4394(11) nm, c = 1.5707(12) nm, β = 106.68(10)°, V = 4.7225(6) nm3, Z = 4, Dc = 3.386g cm-3, R1 = 0.0586, wR2 = 0.1831 (I>2 , GOF = 1.058.

doi:１０．３９６９／ｊ．ｉｓｓｎ．１０００ １５６５．２０１５．０２．００８

Journal of Hebei University (Natural Science Edition) ›› 2015, Vol. 35 ›› Issue (1): 153-.DOI: １０．３９６９／ｊ．ｉｓｓｎ．１０００１５６５．２０１５．０２．００８

Received:2014-09-25 Published:2015-01-25

Abstract

ＬＩＵＸｕｅｍｅｉ，ＷＡＮＧＸｉａｏｆｅｉ，ＬＩＵＭａｎｆｅｉ，ＪＩＡＮＧＦａｎｇ. A new Waugh molybdate formulated as (NH₄)₂(C₅H₆N)₄MnMo₉O₃₂·8H₂O has been isolated by reacting of (NH₄)₆MnMo₉O₃₂·6H₂O and pyridine in aqueous solution, and characterized by single X-ray diffraction, elemental analysis, IR and solid UV-Vis diffuse reflectance spectroscopy. Crystal structural analysis indicate that the title compound crystallizes in the monoclinic system with space group P2₁/c, a = 2.1805(17) nm, b = 1.4394(11) nm, c = 1.5707(12) nm, β = 106.68(10)°, V = 4.7225(6) nm³, Z = 4, D_c = 3.386g cm^-3, R₁ = 0.0586, wR₂ = 0.1831 (I>2 , GOF = 1.058.[J]. Journal of Hebei University (Natural Science Edition), 2015, 35(1): 153-.

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