室内空气气相多溴联苯醚的含量及来源分析

doi:10.3969/j.issn.1000-1565.2018.03.004

河北大学学报(自然科学版) ›› 2018, Vol. 38 ›› Issue (3): 248-253.DOI: 10.3969/j.issn.1000-1565.2018.03.004

室内空气气相多溴联苯醚的含量及来源分析

刘芃岩,许云凤,马傲娟,李占圣,何增浩

收稿日期:2018-01-07 出版日期:2018-05-25 发布日期:2018-05-25
作者简介:刘芃岩(1964—),女,河北保定人,河北大学教授,博士,主要从事环境中典型污染物的生成降解与迁移转化研究. E-mail:hbupyliu@163.com
基金资助:
国家自然科学基金资助项目(21377033);河北省自然科学基金资助项目(B2018201224)

Levels and sources apportionment of gaseous polybrominated diphenyl ethers in indoor air

LIU Pengyan, XU Yunfeng, MA Aojuan, LI Zhansheng, HE Zenghao

College of Chemistry and Environmental Science, Hebei University, Baoding 071002, China

Received:2018-01-07 Online:2018-05-25 Published:2018-05-25

摘要/Abstract

摘要： 利用中流量大气采样器采集了校园7个有代表性的室内空气样品,利用GC-ECD和GC/MS测定多溴联苯醚(polybrominated diphenyl ethers, PBDEs)的种类和含量.结果表明:在所测样品中,共发现14种PBDEs同类物,其中BDE-17、BDE-28、BDE-47、BDE-99、BDE-100、BDE-153、BDE-190的检出率为100%.∑₁₄PBDEs的质量浓度为78.1~414.0 pg/m³,平均质量浓度为266.6 pg/m³,质量浓度最高的同类物是BDE-100.所测室内空气样品中的PBDEs主要以五溴联苯醚污染物为主,其次为八溴联苯醚污染物.不同类型室内空气中PBDEs浓度差异较大,电器数量、家具数量、装修年份是产生差异的重要因素.

关键词: 多溴联苯醚, 气相, 浓度水平, 污染特征, 来源

Abstract: Seven representative indoor air samples were collected using a medium volume sampler on a university campus. The species and concentrations of polybrominated diphenyl ethers(PBDEs)were analyzed using GC-ECD and GC/MS. The results showed that 14 PBDEs were detected in the samples. Among the detected PBDEs, detection of BDE-17, BDE-28, BDE-47, BDE-99, BDE-100, BDE-153, BDE-190 were 100%. The total concentration of PBDEs(∑₁₄PBDEs)ranged from 78.1 to 414.0 pg/m³ with the mean concentration of 266.6 pg/m³, and BDE-100 was the dominant congener. The indoor air pollutants were mainly Penta-BDE, followed by Octa-BDE commercial products. It indicated that PBDEs concentration variations were large in different rooms. The number of electrical equipment, the number of furniture and the year of decoration were important factors to affect the concentration variations of PBDEs.

Key words: polybrominated diphenyl ethers, gas phase, concentrations, pollution characteristics, sources

中图分类号:

刘芃岩,许云凤,马傲娟,李占圣,何增浩. 室内空气气相多溴联苯醚的含量及来源分析[J]. 河北大学学报(自然科学版), 2018, 38(3): 248-253.

LIU Pengyan, XU Yunfeng, MA Aojuan, LI Zhansheng, HE Zenghao. Levels and sources apportionment of gaseous polybrominated diphenyl ethers in indoor air[J]. Journal of Hebei University (Natural Science Edition), 2018, 38(3): 248-253.

参考文献

[1] YANG M,JIA H L, MA W L, et al. Levels, compositions, and gas-particle partitioning of polybrominated diphenyl ethers and dechlorane plus in air in a Chinese northeastern city[J].Atmospheric Environment, 2012, 55: 73-79. DOI:10.1021/es052123v.
[2] MANDALAKIS M, STEPHANOU E G, HORII Y, et al. Emerging contaminants in car interiors:Evaluating the impact of airborne PBDEs and PBDD/Fs [J]. Environmental Science and Technology, 2008, 42(17): 6431-6436. DOI:10.1021/es7030533.
[3] BIRNBAUM L S, STASKAL D F. Brominated flame retardants:Cause for concern[J]. Environmental Health Perspectives, 2004, 112(1):9-17. DOI:10.1289/ehp.6559.
[4] RUDEL R A, DODSON R E, PEROVICH L J, et al. Semivolatile endocrine-disrupting compounds in paired indoor and outdoor air in two Northern California communities [J]. Environmental Science and Technology, 2010, 44(17):6583-6590. DOI:10.1021/es100159c.
[5] 刘芃岩,杨金新,王永慧,等. 水相中2,2’,4,4’-四溴联苯醚微波降解的影响因素[J].河北大学学报(自然科学版),2017,37(1):24-30,38. DOI:10.3969/j.issn.1000-1565.2017.01.005. LIU P Y, YANG J X, WANG Y H, et al. Influencing factors of microwave degradation of 2,2’,4,4’-tetrabromodiphenyl ether in aqueous solution[J]. Journal of Hebei University(Natural Science Edition),2017, 37(1): 24-30.38. DOI:10.3969/j.issn.1000-1565.2017.01.005.
[6] CHEN L G, MAI B X, XU Z C, et al. In-and outdoor sources of polybrominated diphenyl ethers and their human inhalation exposure in Guangzhou,China [J]. Atmospheric Environment, 2008,42(1):78-86. DOI:10.1016/j.atmosenv.2007.09.010.
[7] 孙鑫,陈颖,王云华,等. 杭州市家庭室内空气中PBDEs的污染现状与特征[J]. 环境科学学报,2013,33(2):364-369. DOI:10.13671/jhjkxxb.2013.02.037. SUN X, CHEN Y, WANG Y H,et al. Pollution status and characteristics of PBDEs in indoor air in Hangzhou [J]. Acta Scientiae Circumstantiae, 2013,33(2):364-369. DOI:10.13671/jhjkxxb.2013.02.037.
[8] 刘洋.上海市室内空气中多溴联苯醚污染状况及甲状腺干扰活性的初步研究[D]. 上海:东华大学,2011.
[9] SJODIN A, JAKOBSSON E, KIERKEGAURD A, et al. Gas chromatographic identification and quantification of polybriminated diphenyl ethers in a commercial product, Bromkal 70-5DE[J]. Journal of Chromatography A, 1998,822(1):83-89. DOI:10.1016/S0021-9673(98)00614-1.
[10] PREVEDOUROS K, JONES K C, SWEETMAN A J,et al. Estimation of the production, consumption, and atmospheric emissions of pentabriminated diphenyl ethers inEurope between 1970 and 2000 [J]. Environmental Science Technology, 2004,38:3224-3231. DOI:10.1021/es049711d.
[11] WILFORD B H, HARNER T, ZHU J P, et al. Passive sampling survey of polybrominated diphenyl ether flame retardants in indoor and outdoor air in Ottawa, Canada: Implications for sources and exposure [J]. Environmental Science Technology, 2004, 38:5312-5318. DOI:10.1021/es049260x.
[12] HARRAD S, WIJESEKERA R, HUNTER S, et al. Preliminary assessment of U.K. human dietary and inhalation exposure to polybrominated diphenyl ethers [J]. Environmental Science Technology, 2004,38:2345-2350. DOI:10.1021/es0301121.
[13] GEVAO B, AI-BAHLOUL M, Al-GHADBAN A N, et al. Polybrominated diphenyl ethers in indoor air in Kuwait: Implications for human exposure [J]. Atmospheric Environment, 2006,40(8):1419-1426. DOI:10.1016/j.atmosenv.2005.10.053.
[14] ALAEE M, ARIAS P, SJODIN A, et al. An overview of commercially used brominated flame retardants, their applications, their use patterns in different contries/regions and possible modes of release [J]. Environment International, 2003, 29(6):683-689. DOI:10.1016/S0160-4120(03)00121-1.

[1]	葛嘉雨,梁海燕,刘冬,李春灵,张丰泉,赵茜. 柱前衍生-SPE-GC/MS法测定水中痕量溴代苯酚[J]. 河北大学学报(自然科学版), 2022, 42(4): 395-402.
[2]	杨华美,蒋菊,刘望,张秉哲,徐盼盼. 纤维素/木质素共热解过程中的气相反应[J]. 河北大学学报(自然科学版), 2022, 42(3): 273-280.
[3]	何增浩,王晓冰,刘芃岩,巩一潮,朱爱雪,牛玥. 污水处理厂各构筑物中多溴联苯醚的去除[J]. 河北大学学报(自然科学版), 2020, 40(2): 137-143.
[4]	赵娜,孙月娜,时丽艳,李攀,吕运开. 化妆品塑料包装中16种增塑剂的迁移规律[J]. 河北大学学报(自然科学版), 2019, 39(3): 270-277.
[5]	张琪,马瑶佳,艾连峰,吕运开. 基于轻质萃取剂的涡旋辅助分散液液微萃取-气相色谱法测定瓶装水中塑化剂[J]. 河北大学学报(自然科学版), 2018, 38(1): 33-40.
[6]	马永青,李小盼,孔亚萍,杨会龙,李亚丽. [J]. 河北大学学报(自然科学版), 2016, 36(5): 487-493.
[7]	王庭欣,王光冲. 腐竹中乌洛托品的高效气相色谱检测技术[J]. 河北大学学报(自然科学版), 2013, 33(5): 477-483.
[8]	孙汉文,李挥,康占省,张敬轩,吕运开. 气相色谱-质谱法同时检测婴幼儿配方奶粉中的6种雌激素残留[J]. 河北大学学报(自然科学版), 2011, 31(6): 607-611.
[9]	于涛,黄海清. 固相萃取-气相色谱/质谱法测定鄱阳湖枯水期有机污染物[J]. 河北大学学报(自然科学版), 2011, 31(6): 612-616.
[10]	梁淑轩,赵茜,杨中军. 电子垃圾污染地区生物样品中痕量多溴二苯醚的检测[J]. 河北大学学报(自然科学版), 2009, 29(5): 511-517.
[11]	刘芃岩,李睿,陈晓景,刘玉涛. 塑料包装材料中内分泌干扰素邻苯二甲酸酯类物质的测定[J]. 河北大学学报(自然科学版), 2009, 29(3): 284-290.
[12]	赵玉,杨更亮,曹伟敏,白立改,朱涛,李风新,姜明明. 顶空-固相微萃取-毛细管气相色谱法检测土壤中的苯系物[J]. 河北大学学报(自然科学版), 2008, 28(3): 276-281.
[13]	赵燕燕,王翠玲,白洁,苏芳,韩媛媛,李月秋. 毛细管气相色谱法测定几种中草药中啶虫眯的痕量残留[J]. 河北大学学报(自然科学版), 2008, 28(3): 272-275.
[14]	李杰,李楠,李国锋,吴彦. 气相脉冲放电针-板反应器降解水中有机物[J]. 河北大学学报(自然科学版), 2007, 27(6): 646-649.
[15]	阎正,陈培云,崔建波,张建申. 气液色谱填充柱双抽涂渍法[J]. 河北大学学报(自然科学版), 2007, 27(1): 46-49.

室内空气气相多溴联苯醚的含量及来源分析

Levels and sources apportionment of gaseous polybrominated diphenyl ethers in indoor air

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价