苯酚加氢研究进展

doi:10.3969/j.issn.1000-1565.2018.03.003

摘要/Abstract

摘要： 环己酮/环己醇是重要的化工原料,是生产大宗商品尼龙6和尼龙66的重要中间体. 苯酚加氢法制取环己酮和环己醇,因具有能耗低、原子经济性好、选择性好等特点而被研究工作者广泛研究. 本文主要介绍了苯酚的加氢机理,综述了该反应中不同种类的金属催化剂,总结了其在苯酚加氢制取环己醇和环己酮反应的最新研究进展,并指出了苯酚加氢反应存在的问题和发展方向.

关键词: 苯酚, 加氢, 催化剂, 环己醇, 环己酮

Abstract: Cyclohexanol and cyclohexanone are important chemical raw materials, which are the key intermediates in the manufacture of nylon 6 and nylon 66. The hydrogenation of phenol to cyclohexanol or cyclohexanone has attracted much attention due to its low energy consumption, good atom economy and good selectivity. In this review, the hydrogenation mechanism of phenol is introduced, and the different kinds of metal catalysts in the hydrogenation of phenol are reviewed. Finally, the problems and development strategies in phenol hydrogenation are also discussed.

Key words: phenol, hydrogenation, catalyst, cyclohexanol, cyclohexanone

中图分类号:

温昕,董洁,舍添添,白国义. 苯酚加氢研究进展[J]. 河北大学学报(自然科学版), 2018, 38(3): 239-247.

WEN Xin, DONG Jie, SHE Tiantian, BAI Guoyi. Progress in phenol hydrogenation[J]. Journal of Hebei University (Natural Science Edition), 2018, 38(3): 239-247.

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