Adsorption of tungsten by N-doped lignin

doi:10.3969/j.issn.1000-1565.2024.03.006

Abstract

Abstract: N-doped lignin used for adsorption of tungsten was synthesized by polyamination and quaternization from lignin. The adsorbent was characterized by SEM-EDS and FTIR. The effects of pH, initial mass concentration of tungsten, adsorption time and amount of adsorbent on the adsorption capacity were investigated. The adsorption mechanism was revealed by SEM-EDS and FTIR and XPS. The results showed that N-doped lignin was loose and porous and contained a large amount of phenolic hydroxyl, amine and quaternary ammonium functional groups. When the total concentration of tungsten was 0.005 mol/L and the value of pH was smaller than 4.7, the existing form of tungsten was H₂W₁₂O^6-₄₀. H₂W₁₂O^6-₄₀ was adsorbed by N-doped lignin through electrostatic attraction of hydrogen bond and coordination with amino and ion exchange with Cl^-. The saturated adsorption capacity of 1 g/L N-doped lignin for tungsten reached 421.68 mg/g at pH of 4.0, with initial tungsten mass concentration of 800 mg/L and adsorption time of 960 min. The adsorption followed Langmuir model and quasi-second-order kinetic model, indicating that the adsorption was monolayer homogeneous chemisorption.

Key words: N-doped lignin, tungsten, adsorption behavior, adsorption mechanism

CLC Number:

TF839

ZHANG Baoping, KE Jing, FANG Shiyuan, LI Wencan. Adsorption of tungsten by N-doped lignin[J]. Journal of Hebei University(Natural Science Edition), 2024, 44(3): 269-280.

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