Perfluorosulfonic acid resin modified ZSM-5 zeolite as catalyst for cyclohexene hydration

doi:10.3969/j.issn.1000-1565.2025.01.007

Abstract

Abstract: A series xHNF/ZSM-5(where x represents the mass fraction of sulfonic acid resin in the catalyst)composite catalysts were prepared by loading perfluorosulfonic acid resin on ZSM-5 using the impregnation method and applied in the hydration of cyclohexene to produce cyclohexanol. The physicochemical properties of corresponding catalysts were studied by BET, XRD, TEM, and Py-IR. In addition, the influence of reaction condition was also investigated in this work. It was found that with reaction temperature of 125 ℃, 0.4 MPa of nitrogen pressure and the reaction time of 120 min, a 12.9% cyclohexene conversion with the selectivity of cyclohexanol over 99% could achieved with 20HNF/ZSM-5, which is the optimal catalyst in this reaction. Meanwhile, the conversion rate of cyclohexene remained above 10% for the 20HNF/ZSM-5 catalyst with five cycles, indicating its excellent stability during reaction.

Key words: ZSM-5, perfluorosulfonic acid resin, cyclohexene hydration, cyclohexanol

CLC Number:

O643.36

NIU Libo, XUE Yulian, ZHANG Qian, WANG Yatao, XU Zhaozhong, CHEN Yi, LYU Yunkai. Perfluorosulfonic acid resin modified ZSM-5 zeolite as catalyst for cyclohexene hydration[J]. Journal of Hebei University(Natural Science Edition), 2025, 45(1): 60-69.

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