Q235扁钢接地材料杂散电流腐蚀行为研究

doi:10.3969/j.issn.1000-1565.2016.05.008

摘要/Abstract

摘要： 针对接地网服役过程中的杂散电流腐蚀问题,在模拟交、直流杂散电流干扰条件下,研究了Q235扁钢接地材料的腐蚀行为,利用扫描电镜(SEM)和X线衍射(XRD)等方法研究了材料的腐蚀形貌及腐蚀产物,分析了材料的电位、电流变化规律及腐蚀失重.结果表明:杂散电流腐蚀具有集中腐蚀特征,腐蚀产物层疏松多孔,有明显裂纹、分层、脱落现象,对基体不具有保护作用,腐蚀产物主要成分为Fe₃O₄和Fe₂O₃;失重测量结果显示,杂散电流存在时Q235扁钢腐蚀速率会大大增加,同等电流密度下,直流杂散电流腐蚀速率约为交流杂散电流的18倍;杂散电流腐蚀具有明显的电解腐蚀特征,电流流入金属构件部位成为阴极而受到保护,相反电流流出的部位成为阳极而受到腐蚀.

关键词: Q235扁钢, 杂散电流, 腐蚀产物, 腐蚀速率

Abstract: On the base of stray current corrosion(SCC)problems in the grounding grid service process,the corrosion behavior of Q235 carbon steel grounding material under simulation of AC or DC stray current interference conditions was studied by means of potential,current and corrosion weight loss measurement,and the corrosion morphology and products were characterized by SEM and XRD.The results showed that SCC had concentrated corrosion characteristics and the AC or DC SCC product layer was porous and had obvious crack,delamination and detachment,which implies its uselessness to protect the matrix.The corrosion products mainly consisted of Fe₃O₄ and Fe₂O₃.The results of weight loss measurement showed that the corrosion rate of Q235 steel was increased under AC or DC stay current interference conditions and the corrosion rate of DC SCC was about 18 times of AC SCC under the same current density.SCC- 2016年河北大学学报(自然科学版) 2016第36卷第5期 Journal of Hebei University(Natural Science Edition) Vol.36 No.5DOI:10.3969/j.issn.1000-1565.2016.05.008Q235扁钢接地材料杂散电流腐蚀行为研究祝郦伟¹,杨丙坤²,刘敏¹,胡家秀^2,3,钱洲亥¹(1.国网浙江省电力公司电力科学研究院,浙江杭州 310006;2.中国科学院金属研究所,辽宁沈阳 110016;3.国家金属腐蚀控制工程技术研究中心,辽宁沈阳 110016)摘要:针对接地网服役过程中的杂散电流腐蚀问题,在模拟交、直流杂散电流干扰条件下,研究了Q235扁钢接地材料的腐蚀行为,利用扫描电镜(SEM)和X线衍射(XRD)等方法研究了材料的腐蚀形貌及腐蚀产物,分析了材料的电位、电流变化规律及腐蚀失重.结果表明:杂散电流腐蚀具有集中腐蚀特征,腐蚀产物层疏松多孔,有明显裂纹、分层、脱落现象,对基体不具有保护作用,腐蚀产物主要成分为Fe₃O₄和Fe₂O₃;失重测量结果显示,杂散电流存在时Q235扁钢腐蚀速率会大大增加,同等电流密度下,直流杂散电流腐蚀速率约为交流杂散电流的18倍;杂散电流腐蚀具有明显的电解腐蚀特征,电流流入金属构件部位成为阴极而受到保护,相反电流流出的部位成为阳极而受到腐蚀.关键词:Q235扁钢;杂散电流;腐蚀产物;腐蚀速率中图分类号:TG174 文献标志码:A 文章编号:1000-1565(2016)05-0494-07Stray current corrosion behavior of Q235carbon steel grounding materialZHU Liwei¹,YANG Bingkun²,LIU Min¹,HU Jiaxiu^2,3,QIAN Zhouhai¹(1.State Grid Zhejiang Province Electric Power Research Institute,Hangzhou 310006,China;2.Institute of Metal Research,Chinese Academy of Sciences,Shenyang 110016,China;3.National Engineering Technical Research Center for Metal Corrosion Control,Shenyang 110016,China)Abstract: On the base of stray current corrosion(SCC)problems in the grounding grid service process,the corrosion behavior of Q235 carbon steel grounding material under simulation of AC or DC stray current interference conditions was studied by means of potential,current and corrosion weight loss measurement,and the corrosion morphology and products were characterized by SEM and XRD.The results showed that SCC had concentrated corrosion characteristics and the AC or DC SCC product layer was porous and had obvious crack,delamination and detachment,which implies its uselessness to protect the matrix.The corrosion products mainly consisted of Fe₃O₄ and Fe₂O₃.The results of weight loss measurement showed that the corrosion rate of Q235 steel was increased under AC or DC stay current interference conditions and the corrosion rate of DC SCC was about 18 times of AC SCC under the same current density.SCC- 收稿日期:2015-10-21 基金项目:国家自然科学基金重大项目(50499333);国家电网公司重点科技项目资助(5211DS120348) 第一作者:祝郦伟(1979—),男,浙江杭州人,国网浙江省电力公司电力科学研究院高级工程师,主要从事电力系统腐蚀与防护技术研究.E-mail:wwlyz@163.com 通信作者:杨丙坤(1988—),男,河北沧州人,中国科学院金属研究所在读硕士研究生,主要从事金属材料土壤腐蚀与防护技术研究.E-mail:bkyang13s@imr.ac.cn第5期祝郦伟等:Q235扁钢接地材料杂散电流腐蚀行为研究河北大学学报(自然科学版) 第36卷had obvious electrolytic corrosion characteristics.The area where current flowing into was protected as the cathode and the current outflow area was corroded as the anode.

Key words: Q235 carbon steel, stray current, corrosion product, corrosion rate

中图分类号:

TG174

祝郦伟,杨丙坤,刘敏,胡家秀,钱洲亥. Q235扁钢接地材料杂散电流腐蚀行为研究[J]. 河北大学学报(自然科学版), 2016, 36(5): 494-500.

ZHU Liwei,YANG Bingkun,LIU Min,HU Jiaxiu,QIAN Zhouhai. Stray current corrosion behavior of Q235 carbon steel grounding material[J]. Journal of Hebei University (Natural Science Edition), 2016, 36(5): 494-500.

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